1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-heptylbenzene

Base Information

Chemical Name:1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-heptylbenzene
CAS No.:404872-03-3
Molecular Formula:C₃₁H₅₆O₃Si₂
Molecular Weight:532.955
Hs Code.:

Synonyms:1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-heptylbenzene

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Chemical Property of 1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-heptylbenzene

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Technology Process of 1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-heptylbenzene

There total 1 articles about 1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-heptylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: p-heptylphenylmagnesium bromide

: 201232-73-7
p-tert-butylphenyl 4,6-di-O-tert-butyl(dimethyl)silyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside

: 404872-03-3
1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-heptylbenzene

Guidance literature:: With 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; In tetrahydrofuran; at -40 ℃; for 24h;

Reference yield: 60.0%

: 404872-03-3
1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-heptylbenzene

: 404872-09-9
1-(2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl)-4-n-heptylbenzene

Guidance literature:: With tetrabutyl-ammonium chloride; In tetrahydrofuran; at 25 ℃; for 2h;

Reference yield:

: 404872-03-3
1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-heptylbenzene

: (1S,6R,8R)-8-(4-n-heptylphenyl)-3-(4-n-hexyloxyphenyl)-2,4,7-trioxa-3-borabicyclo[4.4.0]decane

Guidance literature:: Multi-step reaction with 3 steps

1: 60 percent / tetrabutylammonium chloride trihydrate / tetrahydrofuran / 2 h / 25 °C

2: 76 percent / H₂ / [Rh(COD)(1,4-bis(diphenylphosphino)butane)]ClO₄ / ethanol / 24 h / 20 °C / atmospheric pressure

3: 75 percent / toluene / 45 °C / 45 Torr

With tetrabutyl-ammonium chloride; hydrogen; [Rh(COD)(1,4-bis(diphenylphosphino)butane)]ClO₄; In tetrahydrofuran; ethanol; toluene;