(2R,3S)-1,1-diethyl 3-methyl 2-(2-bromophenyl)-3-(diphenylmethyleneamino)propane-1,1,3-tricarboxylate

Base Information

Chemical Name:(2R,3S)-1,1-diethyl 3-methyl 2-(2-bromophenyl)-3-(diphenylmethyleneamino)propane-1,1,3-tricarboxylate
CAS No.:1312929-63-7
Molecular Formula:C₃₀H₃₀BrNO₆
Molecular Weight:580.475
Hs Code.:

Synonyms:(2R,3S)-1,1-diethyl 3-methyl 2-(2-bromophenyl)-3-(diphenylmethyleneamino)propane-1,1,3-tricarboxylate

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Chemical Property of (2R,3S)-1,1-diethyl 3-methyl 2-(2-bromophenyl)-3-(diphenylmethyleneamino)propane-1,1,3-tricarboxylate

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Technology Process of (2R,3S)-1,1-diethyl 3-methyl 2-(2-bromophenyl)-3-(diphenylmethyleneamino)propane-1,1,3-tricarboxylate

There total 1 articles about (2R,3S)-1,1-diethyl 3-methyl 2-(2-bromophenyl)-3-(diphenylmethyleneamino)propane-1,1,3-tricarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 93098-67-0
diethyl <(2-bromophenyl)methylene>propanedioate

: 81167-39-7
methyl N-(diphenylmethylene)glycinate

: 1312929-63-7
(2R,3S)-1,1-diethyl 3-methyl 2-(2-bromophenyl)-3-(diphenylmethyleneamino)propane-1,1,3-tricarboxylate

Guidance literature:: With tetrakis(actonitrile)copper(I) hexafluorophosphate; (Rp)-2-(tert-butylthio)-1-(diphenyl-phosphino)ferrocene; caesium carbonate; In tetrahydrofuran; at 0 ℃; for 6h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1002/chem.201100374

Reference yield:

: 1312929-63-7
(2R,3S)-1,1-diethyl 3-methyl 2-(2-bromophenyl)-3-(diphenylmethyleneamino)propane-1,1,3-tricarboxylate

: 1312929-86-4
(2S,3R)-2-(1-benzhydryl-2-methoxycarbonyl-2,3-dihydro-1H-indol-3-yl)malonic acid diethyl ester

: 2-(1-benzhydryl-2-methoxycarbonyl-2,3-dihydro-1H-indol-3-yl)malonic acid diethyl ester

Guidance literature:: (2R,3S)-1,1-diethyl 3-methyl 2-(2-bromophenyl)-3-(diphenylmethyleneamino)propane-1,1,3-tricarboxylate; With tri-n-butyl-tin hydride; In benzene; at 80 ℃; Inert atmosphere;

With 2,2'-azobis(isobutyronitrile); In benzene; at 80 ℃; for 3h; optical yield given as %de; Inert atmosphere;
DOI:10.1002/chem.201100374