anti-11-carbomethoxy-3-(3-((tert-butyldimethylsilyl)oxy)phenyl)-1,6-methano<10>annulene

Base Information

Chemical Name:anti-11-carbomethoxy-3-(3-((tert-butyldimethylsilyl)oxy)phenyl)-1,6-methano<10>annulene
CAS No.:142566-77-6
Molecular Formula:C₂₅H₃₀O₃Si
Molecular Weight:406.597
Hs Code.:

Synonyms:anti-11-carbomethoxy-3-(3-((tert-butyldimethylsilyl)oxy)phenyl)-1,6-methano<10>annulene

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Chemical Property of anti-11-carbomethoxy-3-(3-((tert-butyldimethylsilyl)oxy)phenyl)-1,6-methano<10>annulene

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Technology Process of anti-11-carbomethoxy-3-(3-((tert-butyldimethylsilyl)oxy)phenyl)-1,6-methano<10>annulene

There total 2 articles about anti-11-carbomethoxy-3-(3-((tert-butyldimethylsilyl)oxy)phenyl)-1,6-methano<10>annulene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 142566-72-1
methyl 4-(3-((tert-butyldimethylsilyl)oxy)phenyl)<4.4.1>propella-2,8-diene-11-carboxylate

: 142566-77-6
anti-11-carbomethoxy-3-(3-((tert-butyldimethylsilyl)oxy)phenyl)-1,6-methano<10>annulene

Guidance literature:: With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In 1,4-dioxane; 1.) 60-70 deg C, 2.) reflux, 24 h;
DOI:10.1021/ja00043a046

Reference yield:

: 142566-67-4
4-(3-((tert-butyldimethylsilyl)oxy)phenyl)<4.4.1>propella-2,8-diene-11-carboxylic acid

: 142566-77-6
anti-11-carbomethoxy-3-(3-((tert-butyldimethylsilyl)oxy)phenyl)-1,6-methano<10>annulene

Guidance literature:: Multi-step reaction with 2 steps

1: K₂CO₃ / acetonitrile / 3 h / Ambient temperature

2: DDQ / dioxane / a) from 60 deg C to 70 deg C, 41 h, b) reflux, 24 h

With potassium carbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In 1,4-dioxane; acetonitrile;
DOI:10.1021/ja00102a020