dibenzyl [({2-[(1R,2R,4S)-2-hydroxy-1,3,3-trimethylbicyclo[2.2.1]hept-2-yl]ethyl}amino)methylylidene]biscarbamate

Base Information

Chemical Name:dibenzyl [({2-[(1R,2R,4S)-2-hydroxy-1,3,3-trimethylbicyclo[2.2.1]hept-2-yl]ethyl}amino)methylylidene]biscarbamate
CAS No.:1602487-81-9
Molecular Formula:C₂₉H₃₇N₃O₅
Molecular Weight:507.63
Hs Code.:

Synonyms:dibenzyl [({2-[(1R,2R,4S)-2-hydroxy-1,3,3-trimethylbicyclo[2.2.1]hept-2-yl]ethyl}amino)methylylidene]biscarbamate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of dibenzyl [({2-[(1R,2R,4S)-2-hydroxy-1,3,3-trimethylbicyclo[2.2.1]hept-2-yl]ethyl}amino)methylylidene]biscarbamate

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of dibenzyl [({2-[(1R,2R,4S)-2-hydroxy-1,3,3-trimethylbicyclo[2.2.1]hept-2-yl]ethyl}amino)methylylidene]biscarbamate

There total 3 articles about dibenzyl [({2-[(1R,2R,4S)-2-hydroxy-1,3,3-trimethylbicyclo[2.2.1]hept-2-yl]ethyl}amino)methylylidene]biscarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 25508-20-7
N,N'-dibenzyloxycarbonyl-(S)-methyl-isothiourea

: 366014-01-9
(1R,2R)-2-(2-aminoethyl)-2-hydroxy-1,3,3-trimethylbicyclo[2.2.1]heptane

: 1602487-81-9
dibenzyl [({2-[(1R,2R,4S)-2-hydroxy-1,3,3-trimethylbicyclo[2.2.1]hept-2-yl]ethyl}amino)methylylidene]biscarbamate

Guidance literature:: With potassium carbonate; In tetrahydrofuran; at 20 ℃; for 168h;
DOI:10.1016/j.ejmech.2014.03.025

Reference yield:

: 7787-20-4,126-21-6
(1R)-fenchone

: 1602487-81-9
dibenzyl [({2-[(1R,2R,4S)-2-hydroxy-1,3,3-trimethylbicyclo[2.2.1]hept-2-yl]ethyl}amino)methylylidene]biscarbamate

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 0.75 h / -85 °C / Inert atmosphere

1.2: 1 h / -85 °C / Inert atmosphere

2.1: lithium aluminium tetrahydride / diethyl ether

3.1: potassium carbonate / tetrahydrofuran / 168 h / 20 °C

With lithium aluminium tetrahydride; n-butyllithium; potassium carbonate; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1016/j.ejmech.2014.03.025

Reference yield:

: 366013-96-9,324538-17-2,439689-16-4
2-((1R,2R,4S)-2-hydroxy-1,3,3-trimethylbicyclo[2.2.1]heptan-2-yl)acetonitrile

: 1602487-81-9
dibenzyl [({2-[(1R,2R,4S)-2-hydroxy-1,3,3-trimethylbicyclo[2.2.1]hept-2-yl]ethyl}amino)methylylidene]biscarbamate

Guidance literature:: Multi-step reaction with 2 steps

1: lithium aluminium tetrahydride / diethyl ether

2: potassium carbonate / tetrahydrofuran / 168 h / 20 °C

With lithium aluminium tetrahydride; potassium carbonate; In tetrahydrofuran; diethyl ether;
DOI:10.1016/j.ejmech.2014.03.025