(S)-N-(diphenylphosphinyl)-6,7,8,9-tetrahydro-5H-benzocyclohepten-5-ylamine

Base Information

Chemical Name:(S)-N-(diphenylphosphinyl)-6,7,8,9-tetrahydro-5H-benzocyclohepten-5-ylamine
CAS No.:259729-25-4
Molecular Formula:C₂₃H₂₄NOP
Molecular Weight:361.423
Hs Code.:

Synonyms:(S)-N-(diphenylphosphinyl)-6,7,8,9-tetrahydro-5H-benzocyclohepten-5-ylamine

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Chemical Property of (S)-N-(diphenylphosphinyl)-6,7,8,9-tetrahydro-5H-benzocyclohepten-5-ylamine

Chemical Property:

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Technology Process of (S)-N-(diphenylphosphinyl)-6,7,8,9-tetrahydro-5H-benzocyclohepten-5-ylamine

There total 3 articles about (S)-N-(diphenylphosphinyl)-6,7,8,9-tetrahydro-5H-benzocyclohepten-5-ylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 192461-81-7
N-(6,7,8,9-tetrahydro-5H-benzocyclohepten-5-ylidene)-P,P-diphenylphosphinamide

: (R)-N-(diphenylphosphinyl)-6,7,8,9-tetrahydro-5H-benzocyclohepten-5-ylamine

: 259729-25-4
(S)-N-(diphenylphosphinyl)-6,7,8,9-tetrahydro-5H-benzocyclohepten-5-ylamine

Guidance literature:: With sodium tetrahydroborate; (S,S)-Co(II) complex catalyst (C₄₆H₅₀N₂O₄Co); In ethanol; chloroform; at 0 ℃; for 4h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1246/cl.1997.493

Reference yield:

: 90695-87-7,17910-25-7
benzosuberone oxime

: 259729-25-4
(S)-N-(diphenylphosphinyl)-6,7,8,9-tetrahydro-5H-benzocyclohepten-5-ylamine

Guidance literature:: Multi-step reaction with 2 steps

1: NaBH₄; tetrahydrofurfuryl alcohol; EtOH / (S,S)-cobalt(II) complex / CHCl₃ / 4 h / 0 °C

With Tetrahydrofurfuryl alcohol; sodium tetrahydroborate; ethanol; (S,S)-cobalt(II); In chloroform;
DOI:10.1002/chem.200304794

Reference yield:

: 1499-21-4
Diphenylphosphinic chloride

: 259729-25-4
(S)-N-(diphenylphosphinyl)-6,7,8,9-tetrahydro-5H-benzocyclohepten-5-ylamine

Guidance literature:: Multi-step reaction with 2 steps

1: NaBH₄; tetrahydrofurfuryl alcohol; EtOH / (S,S)-cobalt(II) complex / CHCl₃ / 4 h / 0 °C

With Tetrahydrofurfuryl alcohol; sodium tetrahydroborate; ethanol; (S,S)-cobalt(II); In chloroform;
DOI:10.1002/chem.200304794