benzyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate

Base Information

Chemical Name:benzyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate
CAS No.:355010-36-5
Molecular Formula:C₃₈H₆₄N₂O₉Si₃
Molecular Weight:777.191
Hs Code.:

Synonyms:benzyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate

Suppliers and Price of benzyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of benzyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of benzyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate

There total 4 articles about benzyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

: 100-51-6,185532-71-2
benzyl alcohol

: 355010-40-1
2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranosiduronic acid

: 355010-36-5
benzyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 12h;
DOI:10.1002/1099-0690(200106)2001:11<2129::AID-EJOC2129>3.0.CO;2-#

Reference yield:

: 191352-30-4
(2S,3S,4S,5R,6S)-2-(methoxycarbonyl)-6-(2-(methylamino)-4-nitrophenoxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate

: 355010-36-5
benzyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / aq. NaOH / acetone / 0.08 h / 0 °C

2: 3.68 g / DMAP; pyridine / 48 h / 20 °C

3: 1.83 g / DMAP; DCC / CH₂Cl₂ / 12 h / 20 °C

With pyridine; dmap; sodium hydroxide; dicyclohexyl-carbodiimide; In dichloromethane; acetone;
DOI:10.1016/S0968-0896(03)00108-1

Reference yield:

: 355010-32-1
2-methylamino-4-nitrophenyl-β-D-glucopyranosiduronic acid

: 355010-36-5
benzyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate

Guidance literature:: Multi-step reaction with 2 steps

1: 3.68 g / DMAP; pyridine / 48 h / 20 °C

2: 1.83 g / DMAP; DCC / CH₂Cl₂ / 12 h / 20 °C

With pyridine; dmap; dicyclohexyl-carbodiimide; In dichloromethane;
DOI:10.1016/S0968-0896(03)00108-1