(1S,2R,3S,4R,5R)-methyl 3,4,5-trihydroxy-2-((4-methoxybenzyl)thio)cyclohexanecarboxylate

Base Information

Chemical Name:(1S,2R,3S,4R,5R)-methyl 3,4,5-trihydroxy-2-((4-methoxybenzyl)thio)cyclohexanecarboxylate
CAS No.:1313032-32-4
Molecular Formula:C₁₆H₂₂O₆S
Molecular Weight:342.413
Hs Code.:

Synonyms:(1S,2R,3S,4R,5R)-methyl 3,4,5-trihydroxy-2-((4-methoxybenzyl)thio)cyclohexanecarboxylate

Suppliers and Price of (1S,2R,3S,4R,5R)-methyl 3,4,5-trihydroxy-2-((4-methoxybenzyl)thio)cyclohexanecarboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,2R,3S,4R,5R)-methyl 3,4,5-trihydroxy-2-((4-methoxybenzyl)thio)cyclohexanecarboxylate

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of (1S,2R,3S,4R,5R)-methyl 3,4,5-trihydroxy-2-((4-methoxybenzyl)thio)cyclohexanecarboxylate

There total 3 articles about (1S,2R,3S,4R,5R)-methyl 3,4,5-trihydroxy-2-((4-methoxybenzyl)thio)cyclohexanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 6258-60-2
p-methoxybenzylmercaptan

: 897014-96-9
(-)-methyl 4-epi-shikimate

: 1313032-32-4
(1S,2R,3S,4R,5R)-methyl 3,4,5-trihydroxy-2-((4-methoxybenzyl)thio)cyclohexanecarboxylate

Guidance literature:: With sodium methylate; In methanol; Inert atmosphere;
DOI:10.1021/ol201252x

Reference yield:

: C₂₂H₄₄O₅Si₂

: 1313032-32-4
(1S,2R,3S,4R,5R)-methyl 3,4,5-trihydroxy-2-((4-methoxybenzyl)thio)cyclohexanecarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine hydrofluoride / tetrahydrofuran / 10 h / Inert atmosphere

2: Hoveyda-Grubbs catalyst second generation / dichloromethane; toluene / 50 °C / Inert atmosphere

3: sodium methylate / methanol / Inert atmosphere

With Hoveyda-Grubbs catalyst second generation; pyridine hydrofluoride; sodium methylate; In tetrahydrofuran; methanol; dichloromethane; toluene;
DOI:10.1021/ol201252x

Reference yield:

: 1313032-29-9
(4R,5R,6R)-methyl 2-methylene-4,5,6-trihydroxyoct-7-enoate

: 1313032-32-4
(1S,2R,3S,4R,5R)-methyl 3,4,5-trihydroxy-2-((4-methoxybenzyl)thio)cyclohexanecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: Hoveyda-Grubbs catalyst second generation / dichloromethane; toluene / 50 °C / Inert atmosphere

2: sodium methylate / methanol / Inert atmosphere

With Hoveyda-Grubbs catalyst second generation; sodium methylate; In methanol; dichloromethane; toluene;
DOI:10.1021/ol201252x