tribromodicarbonylbis(dimethylphenylphosphine)rhenium(III)

Base Information

• Chemical Name: tribromodicarbonylbis(dimethylphenylphosphine)rhenium(III)
• CAS No.: 94667-23-9
• Molecular Formula: C₁₈H₂₂Br₃O₂P₂Re
• Molecular Weight: 758.238
• Mol file: 94667-23-9.mol

Synonyms:tribromodicarbonylbis(dimethylphenylphosphine)rhenium(III)

Chemical Property of tribromodicarbonylbis(dimethylphenylphosphine)rhenium(III)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of tribromodicarbonylbis(dimethylphenylphosphine)rhenium(III)

There total 1 articles about tribromodicarbonylbis(dimethylphenylphosphine)rhenium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

fac-[ReBr(CO)3(PPhMe2)2] (26553-93-5,26553-94-6) → tribromodicarbonylbis(dimethylphenylphosphine)rhenium(III) (94667-23-9)

Guidance literature:

With Br₂; In tetrachloromethane; stirring at room temp. under N2 for 2 h; ppt. collected, washed with CCl4, dried in vac., recrystd. from CH2Cl2;elem. anal.;

DOI:10.1016/S0277-5387(00)88057-2

Reference yield:

tribromodicarbonylbis(dimethylphenylphosphine)rhenium(III) (94667-23-9) → fac-[ReBr(CO)3(PPhMe2)2] (26553-93-5,26553-94-6)

Guidance literature:

With AgBF₄ or TlBF₄; In acetone; byproducts: AgBr or TlBr; stirring at room temp.; concg., treating with heptane;

DOI:10.1016/S0277-5387(00)88057-2

upstream raw materials:

fac-[ReBr(CO)3(PPhMe₂)2]

Downstream raw materials:

fac-[ReBr(CO)3(PPhMe₂)2]