methyl 2,3-di-O-benzyl-4-O-(2-bromomethylbenzyl)-6-O-(4-methoxybenzyl)-α-D-glucopyranoside

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Chemical Name:methyl 2,3-di-O-benzyl-4-O-(2-bromomethylbenzyl)-6-O-(4-methoxybenzyl)-α-D-glucopyranoside
CAS No.:1380315-62-7
Molecular Formula:C₃₇H₄₁BrO₇
Molecular Weight:677.632
Hs Code.:

Synonyms:methyl 2,3-di-O-benzyl-4-O-(2-bromomethylbenzyl)-6-O-(4-methoxybenzyl)-α-D-glucopyranoside

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Chemical Property of methyl 2,3-di-O-benzyl-4-O-(2-bromomethylbenzyl)-6-O-(4-methoxybenzyl)-α-D-glucopyranoside

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Technology Process of methyl 2,3-di-O-benzyl-4-O-(2-bromomethylbenzyl)-6-O-(4-methoxybenzyl)-α-D-glucopyranoside

There total 3 articles about methyl 2,3-di-O-benzyl-4-O-(2-bromomethylbenzyl)-6-O-(4-methoxybenzyl)-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 90633-94-6,94827-30-2,90633-89-9
methyl 2,3-di-O-benzyl-6-O-(4-methoxybenzyl)-α-D-glucopyranoside

: 91-13-4
α,α'-dibromo-o-xylene

: 1380315-62-7
methyl 2,3-di-O-benzyl-4-O-(2-bromomethylbenzyl)-6-O-(4-methoxybenzyl)-α-D-glucopyranoside

Guidance literature:: With 18-crown-6 ether; sodium hydride; In dichloromethane; mineral oil; at -10 - 20 ℃; for 14h; Inert atmosphere;
DOI:10.1002/ejoc.201101815

Reference yield:

: 7177-79-9,13035-24-0,29600-81-5,33164-02-2,51842-18-3,52526-59-7,78738-75-7,99212-27-8,101312-02-1,107795-23-3,108739-87-3,129170-92-9,13225-19-9
methyl 2,3-di-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside

: 1380315-62-7
methyl 2,3-di-O-benzyl-4-O-(2-bromomethylbenzyl)-6-O-(4-methoxybenzyl)-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1.1: trifluoroacetic acid / dichloromethane; water / 2 h / 0 °C

2.1: di(n-butyl)tin oxide / toluene / 5 h / Reflux

2.2: 8 h / 90 °C

3.1: 18-crown-6 ether; sodium hydride / dichloromethane; mineral oil / 14 h / -10 - 20 °C / Inert atmosphere

With 18-crown-6 ether; sodium hydride; di(n-butyl)tin oxide; trifluoroacetic acid; In dichloromethane; water; toluene; mineral oil;
DOI:10.1002/ejoc.201101815

Reference yield:

: 17791-36-5
methyl 2,3-di-O-benzyl-α-D-glucopyranoside

: 1380315-62-7
methyl 2,3-di-O-benzyl-4-O-(2-bromomethylbenzyl)-6-O-(4-methoxybenzyl)-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1.1: di(n-butyl)tin oxide / toluene / 5 h / Reflux

1.2: 8 h / 90 °C

2.1: 18-crown-6 ether; sodium hydride / dichloromethane; mineral oil / 14 h / -10 - 20 °C / Inert atmosphere

With 18-crown-6 ether; sodium hydride; di(n-butyl)tin oxide; In dichloromethane; toluene; mineral oil;
DOI:10.1002/ejoc.201101815