benzo[f]tetraphen-2-ol

Base Information

• Chemical Name: benzo[f]tetraphen-2-ol
• CAS No.: 113058-38-1
• Molecular Formula: C₂₂H₁₄O
• Molecular Weight: 294.353
• Mol file: 113058-38-1.mol

Synonyms:Dibenz[a,c]anthracen-2-ol(6CI); 2-Hydroxydibenz[a,c]anthracene

Chemical Property of benzo[f]tetraphen-2-ol

Chemical Property:

• Vapor Pressure: 3.96E-14mmHg at 25°C
• Boiling Point: 581.7°C at 760 mmHg
• Flash Point: 276°C
• Density: 1.312g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of benzo[f]tetraphen-2-ol

There total 19 articles about benzo[f]tetraphen-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

Benzoic acid benzo[b]triphenylen-7-yl ester (118631-92-8) → 2-hydroxy-dibenzanthracene (113058-38-1)

Guidance literature:

With sodium hydroxide; In tetrahydrofuran; methanol; for 0.5h; Ambient temperature;

DOI:10.1021/jo00265a024

Reference yield: 50.0%

2-oxo-1,2,3,4-tetrahydrodibenzanthracene (118631-86-0) → 2-hydroxy-dibenzanthracene (113058-38-1)

Guidance literature:

palladium on activated charcoal; In various solvent(s); for 0.25h; Heating;

DOI:10.1021/jo00265a024

Reference yield:

trans-1,2-bis(benzoyloxy)-1,2,3,4-tetrahydrodibenzanthracene (115348-27-1) → 2-hydroxy-dibenzanthracene (113058-38-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 90 percent / p-toluenesulfonic acid / benzene / 0.5 h / Heating

2: 50 percent / 10percent Pd-C / various solvent(s) / 0.25 h / Heating

With toluene-4-sulfonic acid; palladium on activated charcoal; In benzene;

DOI:10.1021/jo00265a024

upstream raw materials:

2-oxo-1,2,3,4-tetrahydrodibenzanthracene

Benzoic acid benzo[b]triphenylen-7-yl ester

benz<1',2':3,4>anthra<2,1-b>oxepine

(+/-)-2β,4α-dibromo-1,2,3,4-tetrahydrodibenzanthracen-1α-ol

Refernces

• 1、 Kole, Panna L.,Dubey, Sushil K.,Subodh, Kumar. "Synthesis of Isomeric cis-Dihydrodiols and Phenols of Highly Mutagenic Dibenzanthracene". . p. 845 - 849. Retrieved 2007/10/02.