tetracyano-2,2-bipyridine iron (III)

Base Information

• Chemical Name: tetracyano-2,2-bipyridine iron (III)
• CAS No.: 22337-23-1
• Molecular Formula: C₁₄H₈FeN₆
• Molecular Weight: 316.105
• Mol file: 22337-23-1.mol

Synonyms:Ferrate(1-),(2,2'-bipyridine)tetracyano- (8CI); (2,2'-Bipyridine)tetracyanoferrate(1-); Tetracyano(2,2'-bipyridine)ferrate(1-)

Chemical Property of tetracyano-2,2-bipyridine iron (III)

Chemical Property:

• Vapor Pressure: 0.0101mmHg at 25°C
• Boiling Point: 272.5°Cat760mmHg
• Flash Point: 107.2°C
• PSA: 120.94000
• Density: g/cm³
• LogP: 2.52662

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tetracyano-2,2-bipyridine iron (III)

There total 6 articles about tetracyano-2,2-bipyridine iron (III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Fe(2,2-bipyridyl)(CN)4(2-)] → Fe(bpy)(CN)4(1-) (22337-23-1,795217-60-6)

Guidance literature:

In water; Irradiation (UV/VIS); 266 nm laser pulse irradiation, deaerated water; time dependence of the concn. of the initial complex (UV monitoring, various concns.); concn. of hydrated electron formed as a function of laser energy; not isolated (UV detection); Kinetics;

DOI:10.1016/S0020-1693(00)85379-7

Reference yield:

[Fe(2,2-bipyridyl)(CN)4(2-)] + pentacyano(PPh3)ferrate(III)(2-) → Fe(Ph3P)(CN)5(3-) + Fe(bpy)(CN)4(1-) (22337-23-1,795217-60-6)

Guidance literature:

With sodium nitrate; In water; acetone; Electrochem. Process; 25°C, 30% aq.acetone; Kinetics;

Reference yield:

octacyanotungstate(V) (3-) + [Fe(2,2-bipyridyl)(CN)4(2-)] → octacyanotungstate(IV)(4-) + Fe(bpy)(CN)4(1-) (22337-23-1,795217-60-6)

Guidance literature:

With sodium nitrate; In water; acetone; Electrochem. Process; 25°C, 30% aq.acetone; Kinetics;

upstream raw materials:

hydroxyl

Downstream raw materials:

bis-ethoxythiocarbonyldisulfane

disulfiram

Refernces

• 1、 Al-Alousy, Ahmad,Alshehri, Saad,Blandamer, Michael J.,Blundell, Nicholas J.,Burgess, John,et al.. "Solvation and Reactivity of Iron(II)-Diimine Complexes in Dimethyl Sulfoxide-Water Mixtures". . p. 1041 - 1048. Retrieved 1993.
• 2、 Maliyackel,Waltz,Lilie,Woods. "Radiolytic study of the reactions of hydroxyl radical with cobalt(III), iron(II), and ruthenium(II) complexes containing 2,2′-bipyridyl and cyano ligands". . p. 340 - 348. Retrieved 2008/10/08.
• 3、 Kamat, Prashant V.,Lichtin, Norman N.. "Temperature Dependence of Quenching Rates and Efficiencies of Net Forward and Reverse Electron Transfer in the Quenching of Protonated Triplet Methylene Blue by Complexes of Iron(II)". . p. 351 - 353. Retrieved 2007/10/02.