(1S,6S)-ethyl 3-[(1,1-dimethylethyl)dimethylsilyloxy]-1-((S)-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)(hydroxy)methyl)-6-methylcyclohexa-2,4-dienecarboxylate

Base Information

Chemical Name:(1S,6S)-ethyl 3-[(1,1-dimethylethyl)dimethylsilyloxy]-1-((S)-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)(hydroxy)methyl)-6-methylcyclohexa-2,4-dienecarboxylate
CAS No.:1398074-69-5
Molecular Formula:C₂₂H₃₈O₆Si
Molecular Weight:426.626
Hs Code.:

(1S,6S)-ethyl 3-[(1,1-dimethylethyl)dimethylsilyloxy]-1-((S)-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)(hydroxy)methyl)-6-methylcyclohexa-2,4-dienecarboxylate

Synonyms:(1S,6S)-ethyl 3-[(1,1-dimethylethyl)dimethylsilyloxy]-1-((S)-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)(hydroxy)methyl)-6-methylcyclohexa-2,4-dienecarboxylate

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Chemical Property of (1S,6S)-ethyl 3-[(1,1-dimethylethyl)dimethylsilyloxy]-1-((S)-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)(hydroxy)methyl)-6-methylcyclohexa-2,4-dienecarboxylate

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Technology Process of (1S,6S)-ethyl 3-[(1,1-dimethylethyl)dimethylsilyloxy]-1-((S)-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)(hydroxy)methyl)-6-methylcyclohexa-2,4-dienecarboxylate

There total 1 articles about (1S,6S)-ethyl 3-[(1,1-dimethylethyl)dimethylsilyloxy]-1-((S)-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)(hydroxy)methyl)-6-methylcyclohexa-2,4-dienecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.0%

: 1398074-66-2
ethyl 3-[(1,1-dimethylethyl)dimethylsilyloxy]-6-methylcyclohexa-2,4-dienecarboxylate

: 15186-48-8
2,3-isopropylidene-glyceraldehyde

: 1398074-69-5
(1S,6S)-ethyl 3-[(1,1-dimethylethyl)dimethylsilyloxy]-1-((S)-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)(hydroxy)methyl)-6-methylcyclohexa-2,4-dienecarboxylate

: (1S,6R)-ethyl 3-[(1,1-dimethylethyl)dimethylsilyloxy]-1-((R)-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)(hydroxy)methyl)-6-methylcyclohexa-2,4-dienecarboxylate

Guidance literature:: ethyl 3-[(1,1-dimethylethyl)dimethylsilyloxy]-6-methylcyclohexa-2,4-dienecarboxylate; With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere; Molecular sieve;

2,3-isopropylidene-glyceraldehyde; In tetrahydrofuran; hexane; at -78 - -40 ℃; for 0.25h; Inert atmosphere; Molecular sieve;
DOI:10.1021/ol302234a

Reference yield: 68.0%

: 1398074-69-5
(1S,6S)-ethyl 3-[(1,1-dimethylethyl)dimethylsilyloxy]-1-((S)-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)(hydroxy)methyl)-6-methylcyclohexa-2,4-dienecarboxylate

: 1398074-72-0
(1S,6S)-ethyl 3-[(1,1-dimethylethyl)dimethylsilyloxy]-1-((R)-2,2-dimethyl-1,3-dioxolane-4-carbonyl)-6-methylcyclohexa-2,4-dienecarboxylate

Guidance literature:: With sodium hydrogencarbonate; Dess-Martin periodane; In dichloromethane; at 25 ℃; for 1h; Inert atmosphere;
DOI:10.1021/ol302234a