cis-(-)-3'-phenoxybenzyl-2,2-dimethyl-3-hydroxymethyl-cyclopropane carboxylate

Base Information

Chemical Name:cis-(-)-3'-phenoxybenzyl-2,2-dimethyl-3-hydroxymethyl-cyclopropane carboxylate
CAS No.:102681-84-5
Molecular Formula:C₂₀H₂₂O₄
Molecular Weight:326.392
Hs Code.:

Synonyms:cis-(-)-3'-phenoxybenzyl-2,2-dimethyl-3-hydroxymethyl-cyclopropane carboxylate

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Chemical Property of cis-(-)-3'-phenoxybenzyl-2,2-dimethyl-3-hydroxymethyl-cyclopropane carboxylate

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Technology Process of cis-(-)-3'-phenoxybenzyl-2,2-dimethyl-3-hydroxymethyl-cyclopropane carboxylate

There total 4 articles about cis-(-)-3'-phenoxybenzyl-2,2-dimethyl-3-hydroxymethyl-cyclopropane carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 498-15-7,19079-29-9
(+)-Δ³-carene

: 102681-84-5
cis-(-)-3'-phenoxybenzyl-2,2-dimethyl-3-hydroxymethyl-cyclopropane carboxylate

Guidance literature:: Multi-step reaction with 4 steps

1: O₂ / Co(acac)2

2: 70 percent / KMnO₄ / acetic acid; H₂O / 1 h / 25 °C

3: 1.) m-chlorobenzoic acid; 2.) 10percent aq.HCl / 1.) CH₂Cl₂, 25 deg C, 72 h; 2.) CH₃OH, 25 deg C, 18 h

4: 1.) 5percent aq. sodium hydroxide; 2.) triethyl amine / 1.) ethanol, 25 deg C, 1 h; 2.) ethanol, reflux, 3 h

With hydrogenchloride; sodium hydroxide; potassium permanganate; oxygen; triethylamine; 3-chlorobenzoate; cobalt acetylacetonate; In water; acetic acid;
DOI:10.1016/S0040-4020(01)88177-1

Reference yield:

: 22327-32-8
4,7,7-trimethylbicyclo[4.1.0]hept-3-en-2-one

: 102681-84-5
cis-(-)-3'-phenoxybenzyl-2,2-dimethyl-3-hydroxymethyl-cyclopropane carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 70 percent / KMnO₄ / acetic acid; H₂O / 1 h / 25 °C

2: 1.) m-chlorobenzoic acid; 2.) 10percent aq.HCl / 1.) CH₂Cl₂, 25 deg C, 72 h; 2.) CH₃OH, 25 deg C, 18 h

3: 1.) 5percent aq. sodium hydroxide; 2.) triethyl amine / 1.) ethanol, 25 deg C, 1 h; 2.) ethanol, reflux, 3 h

With hydrogenchloride; sodium hydroxide; potassium permanganate; triethylamine; 3-chlorobenzoate; In water; acetic acid;
DOI:10.1016/S0040-4020(01)88177-1

Reference yield:

: 70223-33-5
cis-(-)-3-(2'-oxopropyl)-2,2-dimethyl-cyclopropane-1-carboxylic acid

: 102681-84-5
cis-(-)-3'-phenoxybenzyl-2,2-dimethyl-3-hydroxymethyl-cyclopropane carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) m-chlorobenzoic acid; 2.) 10percent aq.HCl / 1.) CH₂Cl₂, 25 deg C, 72 h; 2.) CH₃OH, 25 deg C, 18 h

2: 1.) 5percent aq. sodium hydroxide; 2.) triethyl amine / 1.) ethanol, 25 deg C, 1 h; 2.) ethanol, reflux, 3 h

With hydrogenchloride; sodium hydroxide; triethylamine; 3-chlorobenzoate;
DOI:10.1016/S0040-4020(01)88177-1