Technology Process of 2,3,4',5,6-pentakis(benzyloxy)-1,1'-biphenyl
There total 4 articles about 2,3,4',5,6-pentakis(benzyloxy)-1,1'-biphenyl which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
tetrakis(triphenylphosphine) palladium(0); sodium carbonate;
In
1,2-dimethoxyethane; ethanol; water;
at 90 ℃;
Inert atmosphere;
DOI:10.1021/jo102228j
- Guidance literature:
-
Multi-step reaction with 2 steps
1: bromine; sodium hydrogencarbonate / dichloromethane / 20 °C / Inert atmosphere
2: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / 1,2-dimethoxyethane; ethanol; water / 90 °C / Inert atmosphere
With
tetrakis(triphenylphosphine) palladium(0); bromine; sodium hydrogencarbonate; sodium carbonate;
In
1,2-dimethoxyethane; ethanol; dichloromethane; water;
DOI:10.1021/jo102228j
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.5 h / 0 - 20 °C / Inert atmosphere
1.2: 2.5 h / 20 °C / Inert atmosphere
2.1: bromine; sodium hydrogencarbonate / dichloromethane / 20 °C / Inert atmosphere
3.1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / 1,2-dimethoxyethane; ethanol; water / 90 °C / Inert atmosphere
With
tetrakis(triphenylphosphine) palladium(0); bromine; sodium hydride; sodium hydrogencarbonate; sodium carbonate;
In
1,2-dimethoxyethane; ethanol; dichloromethane; water; N,N-dimethyl-formamide; mineral oil;
DOI:10.1021/jo102228j
