1-diphenylphosphino-2-phenyl-1,2-dicarba-closo-dodecaborane⁽¹²⁾

Base Information

Chemical Name:1-diphenylphosphino-2-phenyl-1,2-dicarba-closo-dodecaborane⁽¹²⁾
CAS No.:36988-95-1
Molecular Formula:C₂₀H₂₅B₁₀P
Molecular Weight:404.502
Hs Code.:

1-diphenylphosphino-2-phenyl-1,2-dicarba-closo-dodecaborane<sup>(12)</sup>

Synonyms:1-diphenylphosphino-2-phenyl-1,2-dicarba-closo-dodecaborane⁽¹²⁾

Suppliers and Price of 1-diphenylphosphino-2-phenyl-1,2-dicarba-closo-dodecaborane⁽¹²⁾

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-diphenylphosphino-2-phenyl-1,2-dicarba-closo-dodecaborane⁽¹²⁾

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Technology Process of 1-diphenylphosphino-2-phenyl-1,2-dicarba-closo-dodecaborane⁽¹²⁾

There total 2 articles about 1-diphenylphosphino-2-phenyl-1,2-dicarba-closo-dodecaborane⁽¹²⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 16390-61-7
1-phenyl-1,2-closo-C₂B₁₀H₁₁

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 36988-95-1
1-diphenylphosphino-2-phenyl-1,2-dicarba-closo-dodecaborane⁽¹²⁾

Guidance literature:: With MeLi; In diethyl ether; (N2), MeLi soln. dropwise addn. to 1-Ph-1,2-closo-C2B10H11 soln. (273 K), warming (room temp., stirring, 30 min), P(C6H5)2Cl dropwise addn., stirring (30 min), evapn. (vac.); trituration (n-pentane), drying (vac.), recrystn. (n-pentane); elem. anal.;
DOI:10.1107/S0108270196009109

Reference yield:

: 41655-52-1
1-lithia-2-phenyl-1,2-dicarba-closo-dodecaborane

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 36988-95-1
1-diphenylphosphino-2-phenyl-1,2-dicarba-closo-dodecaborane⁽¹²⁾

Guidance literature:: In diethyl ether; at 0-20°C;;

Reference yield: 87.0%

: 36988-95-1
1-diphenylphosphino-2-phenyl-1,2-dicarba-closo-dodecaborane⁽¹²⁾

: 1643-19-2
tetrabutylammomium bromide

: (C₄H₉)4N⁽¹⁺⁾*C₂B₉H₁₀(C₆H₅)P(C₆H₅)2^(1-)=[(C₄H₉)4N][C₂B₉H₁₀(C₆H₅)P(C₆H₅)2]

Guidance literature:: With piperidine; In ethanol; water; toluene; N2-atmosphere; refluxing (26 h), evapn., EtOH and Bu4NBr soln. (H2O) adn.; filtering, washing (H2O, Et2O); elem. anal.;
DOI:10.1021/om9509002