2-O-phenoxythiocarbonyl-3,4-isopropylidene methyl-β-D-arabinopyranoside-2,3,4-²H₃

Base Information

• Chemical Name: 2-O-phenoxythiocarbonyl-3,4-isopropylidene methyl-β-D-arabinopyranoside-2,3,4-²H₃
• CAS No.: 116217-32-4
• Molecular Formula: C₁₆H₂₀O₆S
• Molecular Weight: 343.373

Synonyms:2-O-phenoxythiocarbonyl-3,4-isopropylidene methyl-β-D-arabinopyranoside-2,3,4-²H₃

Chemical Property of 2-O-phenoxythiocarbonyl-3,4-isopropylidene methyl-β-D-arabinopyranoside-2,3,4-²H₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-O-phenoxythiocarbonyl-3,4-isopropylidene methyl-β-D-arabinopyranoside-2,3,4-²H₃

There total 3 articles about 2-O-phenoxythiocarbonyl-3,4-isopropylidene methyl-β-D-arabinopyranoside-2,3,4-²H₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

3,4-isopropylidene methyl-β-D-arabinopyranoside-2,3,4-2H3 (116217-31-3) + phenylcarbonochloridothioate (1005-56-7) → 2-O-phenoxythiocarbonyl-3,4-isopropylidene methyl-β-D-arabinopyranoside-2,3,4-2H3 (116217-32-4)

Guidance literature:

With dmap; In acetonitrile; at 20 ℃;

DOI:10.1016/S0040-4020(01)83465-7

Reference yield:

methyl-β-D-arabinopyranoside (5328-63-2) → 2-O-phenoxythiocarbonyl-3,4-isopropylidene methyl-β-D-arabinopyranoside-2,3,4-2H3 (116217-32-4)

Guidance literature:

Multi-step reaction with 3 steps

1: 33 percent / deuterium oxide / deuterated Raney nickel / 15 h / Heating

2: 90 percent / p-toluenesulfonic acid monohydrate / dimethylformamide / 3 h / 20 °C

3: 86 percent / N,N-dimethylaminopyridine / acetonitrile / 20 °C

With dmap; water-d2; toluene-4-sulfonic acid; deuterated Raney nickel; In N,N-dimethyl-formamide; acetonitrile;

DOI:10.1016/S0040-4020(01)83465-7

Reference yield:

methyl-β-D-arabinopyranoside-2,3,4-2H3 (116217-30-2) → 2-O-phenoxythiocarbonyl-3,4-isopropylidene methyl-β-D-arabinopyranoside-2,3,4-2H3 (116217-32-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 90 percent / p-toluenesulfonic acid monohydrate / dimethylformamide / 3 h / 20 °C

2: 86 percent / N,N-dimethylaminopyridine / acetonitrile / 20 °C

With dmap; toluene-4-sulfonic acid; In N,N-dimethyl-formamide; acetonitrile;

DOI:10.1016/S0040-4020(01)83465-7

upstream raw materials:

3,4-isopropylidene methyl-β-D-arabinopyranoside-2,3,4-²H₃

phenylcarbonochloridothioate

methyl-β-D-arabinopyranoside-2,3,4-²H₃

methyl-β-D-arabinopyranoside

Downstream raw materials:

methyl 2-deoxy-3,5-di-O-p-toluoyl-D-erythro-pentose-2,2',3,4-²H₄

2-deoxy-3,5-di-O-p-toluoyl-D-erythro-pentosyl chloride-2,2',3,4-²H₄

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 116217-32-4 2-O-phenoxythiocarbonyl-3,4-isopropylidene methyl-β-D-arabinopyranoside-2,3,4-²H₃

Send

Send

Metric Ton KG G Pound L ML

Send

Send