(3R,3aS,6S,6aS,8S,9R,9aR,9br)-8-[(4-methoxybenzyl)oxy]-3,6,9-trimethyl-6a,7,8,9,9a,9bhexahydro-6H-3a,6-epidioxyazuleno[4,5-b]furan-2(3H)-one

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Chemical Name:(3R,3aS,6S,6aS,8S,9R,9aR,9br)-8-[(4-methoxybenzyl)oxy]-3,6,9-trimethyl-6a,7,8,9,9a,9bhexahydro-6H-3a,6-epidioxyazuleno[4,5-b]furan-2(3H)-one
CAS No.:1254986-26-9
Molecular Formula:C₂₃H₂₈O₆
Molecular Weight:400.472
Hs Code.:

Synonyms:(3R,3aS,6S,6aS,8S,9R,9aR,9br)-8-[(4-methoxybenzyl)oxy]-3,6,9-trimethyl-6a,7,8,9,9a,9bhexahydro-6H-3a,6-epidioxyazuleno[4,5-b]furan-2(3H)-one

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Chemical Property of (3R,3aS,6S,6aS,8S,9R,9aR,9br)-8-[(4-methoxybenzyl)oxy]-3,6,9-trimethyl-6a,7,8,9,9a,9bhexahydro-6H-3a,6-epidioxyazuleno[4,5-b]furan-2(3H)-one

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Technology Process of (3R,3aS,6S,6aS,8S,9R,9aR,9br)-8-[(4-methoxybenzyl)oxy]-3,6,9-trimethyl-6a,7,8,9,9a,9bhexahydro-6H-3a,6-epidioxyazuleno[4,5-b]furan-2(3H)-one

There total 1 articles about (3R,3aS,6S,6aS,8S,9R,9aR,9br)-8-[(4-methoxybenzyl)oxy]-3,6,9-trimethyl-6a,7,8,9,9a,9bhexahydro-6H-3a,6-epidioxyazuleno[4,5-b]furan-2(3H)-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 1254986-25-8
(3R,6aS,8S,9R,9aS,9br)-8-[(4-methoxybenzyl)oxy]-3,6,9-trimethyl-6a,7,8,9,9a,9b-hexahydroazuleno[4,5-b]furan-2(3H)-one

: 1254986-26-9
(3R,3aS,6S,6aS,8S,9R,9aR,9br)-8-[(4-methoxybenzyl)oxy]-3,6,9-trimethyl-6a,7,8,9,9a,9bhexahydro-6H-3a,6-epidioxyazuleno[4,5-b]furan-2(3H)-one

Guidance literature:: With oxygen; methylene blue; In dichloromethane; at 0 ℃; stereoselective reaction; Inert atmosphere; Irradiation;
DOI:10.1021/jm1006462

Reference yield: 94.0%

: 1254986-26-9
(3R,3aS,6S,6aS,8S,9R,9aR,9br)-8-[(4-methoxybenzyl)oxy]-3,6,9-trimethyl-6a,7,8,9,9a,9bhexahydro-6H-3a,6-epidioxyazuleno[4,5-b]furan-2(3H)-one

: 1254986-28-1
(1R,2S,3aS,4S,7S,8R,8aR)-7-[(1S)-2-hydroxy-1-methylethyl]-2-[(4-methoxybenzyl)oxy]-1,4-dimethyl-1,2,3,3a,4,7,8,8a-octahydro-4,7-epidioxyazulen-8-ol

Guidance literature:: (3R,3aS,6S,6aS,8S,9R,9aR,9br)-8-[(4-methoxybenzyl)oxy]-3,6,9-trimethyl-6a,7,8,9,9a,9bhexahydro-6H-3a,6-epidioxyazuleno[4,5-b]furan-2(3H)-one; With lithium borohydride; In diethyl ether; at 0 - 20 ℃; for 1h; Inert atmosphere;

With water; ammonium chloride; In diethyl ether; Inert atmosphere;
DOI:10.1021/jm1006462

Reference yield: 94.0%

: 1254986-26-9
(3R,3aS,6S,6aS,8S,9R,9aR,9br)-8-[(4-methoxybenzyl)oxy]-3,6,9-trimethyl-6a,7,8,9,9a,9bhexahydro-6H-3a,6-epidioxyazuleno[4,5-b]furan-2(3H)-one

: 1254986-35-0
(3R,3aS,6S,6aS,8S,9R,9aR,9bR)-8-[(4-methoxybenzyl)oxy]-3,6,9-trimethyl-2,3,6a,7,8,9,9a,9b-octahydro-6H-3a,6-epidioxyazuleno[4,5-b]furan-2-ol

Guidance literature:: (3R,3aS,6S,6aS,8S,9R,9aR,9br)-8-[(4-methoxybenzyl)oxy]-3,6,9-trimethyl-6a,7,8,9,9a,9bhexahydro-6H-3a,6-epidioxyazuleno[4,5-b]furan-2(3H)-one; With diisobutylaluminium hydride; In dichloromethane; at -78 ℃; for 0.166667h; Inert atmosphere;

With water; Rochelle's salt; In dichloromethane; at -78 - 20 ℃; for 1h; Inert atmosphere;
DOI:10.1021/jm1006462