(3R)-4-methoxyphenyl 3-[2-(trifluoromethyl)phenyl]-4-nitrobutanethioate

Base Information

Chemical Name:(3R)-4-methoxyphenyl 3-[2-(trifluoromethyl)phenyl]-4-nitrobutanethioate
CAS No.:957770-76-2
Molecular Formula:C₁₈H₁₆F₃NO₄S
Molecular Weight:399.391
Hs Code.:

Synonyms:(3R)-4-methoxyphenyl 3-[2-(trifluoromethyl)phenyl]-4-nitrobutanethioate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3R)-4-methoxyphenyl 3-[2-(trifluoromethyl)phenyl]-4-nitrobutanethioate

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Technology Process of (3R)-4-methoxyphenyl 3-[2-(trifluoromethyl)phenyl]-4-nitrobutanethioate

There total 2 articles about (3R)-4-methoxyphenyl 3-[2-(trifluoromethyl)phenyl]-4-nitrobutanethioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 1353143-26-6
4-methoxybenzyl 3-[(4-methoxyphenyl)sulfanyl]-3-oxopropanoate

: 53960-62-6
2-trifluoromethyl-β-nitrostyrene

: 957770-76-2
(3R)-4-methoxyphenyl 3-[2-(trifluoromethyl)phenyl]-4-nitrobutanethioate

Guidance literature:: 4-methoxybenzyl 3-[(4-methoxyphenyl)sulfanyl]-3-oxopropanoate; 2-trifluoromethyl-β-nitrostyrene; With N-[3,5-bis(trifluoromethyl)phenyl]-N'-[(9R)-6'-methoxycinchonan-9-yl]thiourea; In toluene; at -50 ℃; for 24h;

With trifluoroacetic acid; In dichloromethane; for 2h;

With 1,4-diaza-bicyclo[2.2.2]octane; In dichloromethane; for 1h; optical yield given as %ee; enantioselective reaction;
DOI:10.1039/c1ob06638b

Reference yield:

: 1-(2-nitro-vinyl)-2-trifluoromethyl-benzene

: 428442-20-0
3-[(4-methoxyphenyl)sulfanyl]-3-oxopropanoic acid

: 957770-76-2
(3R)-4-methoxyphenyl 3-[2-(trifluoromethyl)phenyl]-4-nitrobutanethioate

: (3S)-4-methoxyphenyl 3-[2-(trifluormethyl)phenyl]-4-nitrobutanethioate

Guidance literature:: With 1-(3,5-bis-trifluoromethyl-phenyl)-3-epiquinine-urea; In tetrahydrofuran; at 4 ℃; Further Variations:; Solvents; Temperatures; times; Product distribution;
DOI:10.1002/anie.200702187