[⁽¹⁵⁾N]sodium azide

Base Information

• Chemical Name: [⁽¹⁵⁾N]sodium azide
• CAS No.: 111999-55-4
• Molecular Formula: N₃Na
• Molecular Weight: 66.0032
• Mol file: 111999-55-4.mol

Synonyms:[⁽¹⁵⁾N]sodium azide

Chemical Property of [⁽¹⁵⁾N]sodium azide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [⁽¹⁵⁾N]sodium azide

There total 1 articles about [⁽¹⁵⁾N]sodium azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

nitrous oxide (35305-17-0) + sodium amide → [(15)N]sodium azide (111999-55-4) + sodium hydroxide (1310-73-2)

Guidance literature:

byproducts: NH3; formed 22% of (15)NNNNa and 78% of N(15)NNNa;

Reference yield: 90.0%

[(15)N]sodium azide (111999-55-4) + [iron(II)(chloride)(tris-[2-(3-mesityl-imidazol-2-ylidene)ethyl]amine)](hexafluorophosphate) → [iron(IV)((15)nitride)(tris-[2-(3-mesityl-imidazol-2-ylidene)ethyl]amine)](BF4)

Guidance literature:

In acetonitrile; at -30 ℃; for 48h; Darkness; Glovebox; Inert atmosphere;

DOI:10.1021/jacs.0c11141

Reference yield: 80.0%

[(15)N]sodium azide (111999-55-4) + Mo(IV)Cl((3,5-(2,5-diisopropylpyrrolyl)C6H3NCH2CH2)3N) → [Mo(15)N((3,5-(2,5-diisopropylpyrrolyl)C6H3NCH2CH2)3N)]

Guidance literature:

In dioxane; 1,2-dimethoxy-ethane; (inert atm.); stirring mixt. of dioxane soln. of molybdenum compd., sodium azide-(15)N1 and DME at 85°C for 96 h; evapn., drying in vac. at 50°C, extn. (benzene), filtration through celite, concg., layering with pentane, keeping at room temp. overnight and at -30°C for several hs, isolation of crystals, NMR;

DOI:10.1021/ja1008213

upstream raw materials:

nitrous oxide

Downstream raw materials:

(tetraphenylporphyrinato)Mn(⁽¹⁵⁾N-N-N)

(tetraphenylporphyrinato)Mn(N-N-⁽¹⁵⁾N)