methyl 3-<1-(4-chlorobenzyl)-6-hydroxy-4-methyl-4,5-dihydro-1H-thiopyrano<2,3,4-c,d>indol-2-yl>-2,2-dimethylpropanoate S,S-dioxide

Base Information

Chemical Name:methyl 3-<1-(4-chlorobenzyl)-6-hydroxy-4-methyl-4,5-dihydro-1H-thiopyrano<2,3,4-c,d>indol-2-yl>-2,2-dimethylpropanoate S,S-dioxide
CAS No.:147937-15-3
Molecular Formula:C₂₄H₂₆ClNO₅S
Molecular Weight:475.993
Hs Code.:

Synonyms:methyl 3-<1-(4-chlorobenzyl)-6-hydroxy-4-methyl-4,5-dihydro-1H-thiopyrano<2,3,4-c,d>indol-2-yl>-2,2-dimethylpropanoate S,S-dioxide

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Chemical Property of methyl 3-<1-(4-chlorobenzyl)-6-hydroxy-4-methyl-4,5-dihydro-1H-thiopyrano<2,3,4-c,d>indol-2-yl>-2,2-dimethylpropanoate S,S-dioxide

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Technology Process of methyl 3-<1-(4-chlorobenzyl)-6-hydroxy-4-methyl-4,5-dihydro-1H-thiopyrano<2,3,4-c,d>indol-2-yl>-2,2-dimethylpropanoate S,S-dioxide

There total 7 articles about methyl 3-<1-(4-chlorobenzyl)-6-hydroxy-4-methyl-4,5-dihydro-1H-thiopyrano<2,3,4-c,d>indol-2-yl>-2,2-dimethylpropanoate S,S-dioxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 150461-48-6
methyl 3-<6-acetoxy-1-(4-chlorobenzyl)-4-methyl-4,5-dihydro-1H-thiopyrano<2,3,4-c,d>indol-2-yl>-2,2-dimethylpropanoate S,S-dioxide

: 147937-15-3
methyl 3-<1-(4-chlorobenzyl)-6-hydroxy-4-methyl-4,5-dihydro-1H-thiopyrano<2,3,4-c,d>indol-2-yl>-2,2-dimethylpropanoate S,S-dioxide

Guidance literature:: With potassium carbonate; In methanol; at 60 ℃; for 1h;
DOI:10.1021/jm00071a008

Reference yield:

: 144397-00-2
methyl 3-<1-(4-chlorobenzyl)-4-methyl-6-hydroxy-4,5-dihydro-1H-thiopyrano<2,3,4-c,d>indol-2-yl>-2,2-dimethylpropanoate

: 147937-15-3
methyl 3-<1-(4-chlorobenzyl)-6-hydroxy-4-methyl-4,5-dihydro-1H-thiopyrano<2,3,4-c,d>indol-2-yl>-2,2-dimethylpropanoate S,S-dioxide

Guidance literature:: Multi-step reaction with 2 steps

1: 81 percent / pyridine / CH₂Cl₂ / 0.5 h / Ambient temperature

2: 31 mg / 3-chloroperoxybenzoic acid / CH₂Cl₂ / 16 h / Ambient temperature

With pyridine; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/jm00071a008

Reference yield:

: 144396-98-5
methyl 3-<1-(4-chlorobenzyl)-3-(tert-butylthio)-5-(allyloxy)indol-2-yl>-2,2-dimethylpropanoate

: 147937-15-3
methyl 3-<1-(4-chlorobenzyl)-6-hydroxy-4-methyl-4,5-dihydro-1H-thiopyrano<2,3,4-c,d>indol-2-yl>-2,2-dimethylpropanoate S,S-dioxide

Guidance literature:: Multi-step reaction with 3 steps

1: 2.) p-toluenesulfonic acid / 1.) 1,2-dichlorobenzene, reflux, 16 h, 2.) 1,2-dichlorobenzene, 150 deg C, 45 min

2: 81 percent / pyridine / CH₂Cl₂ / 0.5 h / Ambient temperature

3: 31 mg / 3-chloroperoxybenzoic acid / CH₂Cl₂ / 16 h / Ambient temperature

With pyridine; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/jm00071a008