(2E,6Z)-1-(tert-butyldiphenylsilyloxy)-10-chloromethanesulfonyloxy-2,6-decadiene

Base Information

Chemical Name:(2E,6Z)-1-(tert-butyldiphenylsilyloxy)-10-chloromethanesulfonyloxy-2,6-decadiene
CAS No.:307497-78-5
Molecular Formula:C₂₇H₃₇ClO₄SSi
Molecular Weight:521.193
Hs Code.:

Synonyms:(2E,6Z)-1-(tert-butyldiphenylsilyloxy)-10-chloromethanesulfonyloxy-2,6-decadiene

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Chemical Property of (2E,6Z)-1-(tert-butyldiphenylsilyloxy)-10-chloromethanesulfonyloxy-2,6-decadiene

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Technology Process of (2E,6Z)-1-(tert-butyldiphenylsilyloxy)-10-chloromethanesulfonyloxy-2,6-decadiene

There total 4 articles about (2E,6Z)-1-(tert-butyldiphenylsilyloxy)-10-chloromethanesulfonyloxy-2,6-decadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 197219-10-6
(4Z)-8-(4-methoxybenzyloxy)-4-octen-1-ol

: 307497-78-5
(2E,6Z)-1-(tert-butyldiphenylsilyloxy)-10-chloromethanesulfonyloxy-2,6-decadiene

Guidance literature:: Multi-step reaction with 5 steps

1.1: pyridinium chlorochromate; molecular sieves 4A / CH₂Cl₂ / 1.5 h / 25 °C

2.1: benzene / 24 h / 25 °C

2.2: 1.17 g / diisobutylaluminum hydride / CH₂Cl₂; hexane / 1 h / -78 °C

3.1: 97 percent / imidazole / CH₂Cl₂ / 0.5 h / 0 °C

4.1: 81 percent / dichlorodicyanobenzoquinone / CH₂Cl₂; H₂O / 2 h / 25 °C

5.1: 92 percent / pyridine / CH₂Cl₂ / 1.5 h / 0 °C

With pyridine; 1H-imidazole; 4 A molecular sieve; pyridinium chlorochromate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water; benzene; 2.1: Wittig reaction;
DOI:10.1016/S0040-4020(00)00622-0

Reference yield:

: (Z)-8-(4-Methoxy-benzyloxy)-oct-4-enal

: 307497-78-5
(2E,6Z)-1-(tert-butyldiphenylsilyloxy)-10-chloromethanesulfonyloxy-2,6-decadiene

Guidance literature:: Multi-step reaction with 4 steps

1.1: benzene / 24 h / 25 °C

1.2: 1.17 g / diisobutylaluminum hydride / CH₂Cl₂; hexane / 1 h / -78 °C

2.1: 97 percent / imidazole / CH₂Cl₂ / 0.5 h / 0 °C

3.1: 81 percent / dichlorodicyanobenzoquinone / CH₂Cl₂; H₂O / 2 h / 25 °C

4.1: 92 percent / pyridine / CH₂Cl₂ / 1.5 h / 0 °C

With pyridine; 1H-imidazole; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water; benzene; 1.1: Wittig reaction;
DOI:10.1016/S0040-4020(00)00622-0

Reference yield:

: 307497-75-2
(2E,6Z)-10-(4'-methoxybenzyloxy)-2,6-decadien-1-ol

: 307497-78-5
(2E,6Z)-1-(tert-butyldiphenylsilyloxy)-10-chloromethanesulfonyloxy-2,6-decadiene

Guidance literature:: Multi-step reaction with 3 steps

1: 97 percent / imidazole / CH₂Cl₂ / 0.5 h / 0 °C

2: 81 percent / dichlorodicyanobenzoquinone / CH₂Cl₂; H₂O / 2 h / 25 °C

3: 92 percent / pyridine / CH₂Cl₂ / 1.5 h / 0 °C

With pyridine; 1H-imidazole; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water;
DOI:10.1016/S0040-4020(00)00622-0