(3-[tert-butyldimethylsilyloxy]-2,6-dimethylphenyl)(7-isopropenyl-2,2-diphenyl-1,3-benzodioxol-5-yl)methanol

Base Information

Chemical Name:(3-[tert-butyldimethylsilyloxy]-2,6-dimethylphenyl)(7-isopropenyl-2,2-diphenyl-1,3-benzodioxol-5-yl)methanol
CAS No.:1357476-92-6
Molecular Formula:C₃₇H₄₂O₄Si
Molecular Weight:578.824
Hs Code.:

Synonyms:(3-[tert-butyldimethylsilyloxy]-2,6-dimethylphenyl)(7-isopropenyl-2,2-diphenyl-1,3-benzodioxol-5-yl)methanol

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Chemical Property of (3-[tert-butyldimethylsilyloxy]-2,6-dimethylphenyl)(7-isopropenyl-2,2-diphenyl-1,3-benzodioxol-5-yl)methanol

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Technology Process of (3-[tert-butyldimethylsilyloxy]-2,6-dimethylphenyl)(7-isopropenyl-2,2-diphenyl-1,3-benzodioxol-5-yl)methanol

There total 5 articles about (3-[tert-butyldimethylsilyloxy]-2,6-dimethylphenyl)(7-isopropenyl-2,2-diphenyl-1,3-benzodioxol-5-yl)methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 1357476-71-1
3-(tert-butyldimethylsilyloxy)-2,6-dimethylbenzaldehyde

: 1357476-91-5
C₂₂H₁₇BrO₂

: 1357476-92-6
(3-[tert-butyldimethylsilyloxy]-2,6-dimethylphenyl)(7-isopropenyl-2,2-diphenyl-1,3-benzodioxol-5-yl)methanol

Guidance literature:: C₂₂H₁₇BrO₂; With iodine; magnesium; In tetrahydrofuran; Inert atmosphere; Reflux;

3-(tert-butyldimethylsilyloxy)-2,6-dimethylbenzaldehyde; In tetrahydrofuran; at 0 - 20 ℃; for 2h; Inert atmosphere;
DOI:10.1080/00397911.2010.518274

Reference yield:

: 1292688-03-9
3-(tert-butyldimethylsilyloxy)-2,6-dimethylbenzyl alcohol

: 1357476-92-6
(3-[tert-butyldimethylsilyloxy]-2,6-dimethylphenyl)(7-isopropenyl-2,2-diphenyl-1,3-benzodioxol-5-yl)methanol

Guidance literature:: Multi-step reaction with 2 steps

1.1: dipyridinium dichromate / dichloromethane / 3 h / 20 °C

2.1: iodine; magnesium / tetrahydrofuran / Inert atmosphere; Reflux

2.2: 2 h / 0 - 20 °C / Inert atmosphere

With dipyridinium dichromate; iodine; magnesium; In tetrahydrofuran; dichloromethane;
DOI:10.1080/00397911.2010.518274

Reference yield:

: 1292688-12-0
methyl 3-(tert-butyldimethylsilyloxy)-2,6-dimethylbenzoate

: 1357476-92-6
(3-[tert-butyldimethylsilyloxy]-2,6-dimethylphenyl)(7-isopropenyl-2,2-diphenyl-1,3-benzodioxol-5-yl)methanol

Guidance literature:: Multi-step reaction with 3 steps

1.1: diisobutylaluminium hydride / hexane; dichloromethane / -78 °C

2.1: dipyridinium dichromate / dichloromethane / 3 h / 20 °C

3.1: iodine; magnesium / tetrahydrofuran / Inert atmosphere; Reflux

3.2: 2 h / 0 - 20 °C / Inert atmosphere

With dipyridinium dichromate; iodine; diisobutylaluminium hydride; magnesium; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1080/00397911.2010.518274