(1R,2R,3S,4R,5S,6S)-3,4,6-Tris-allyloxy-5-benzyloxy-cyclohexane-1,2-diol

Base Information

• Chemical Name: (1R,2R,3S,4R,5S,6S)-3,4,6-Tris-allyloxy-5-benzyloxy-cyclohexane-1,2-diol
• CAS No.: 141040-46-2
• Molecular Formula: C₂₂H₃₀O₆
• Molecular Weight: 390.477

Synonyms:(1R,2R,3S,4R,5S,6S)-3,4,6-Tris-allyloxy-5-benzyloxy-cyclohexane-1,2-diol

Chemical Property of (1R,2R,3S,4R,5S,6S)-3,4,6-Tris-allyloxy-5-benzyloxy-cyclohexane-1,2-diol

Chemical Property:

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Technology Process of (1R,2R,3S,4R,5S,6S)-3,4,6-Tris-allyloxy-5-benzyloxy-cyclohexane-1,2-diol

There total 16 articles about (1R,2R,3S,4R,5S,6S)-3,4,6-Tris-allyloxy-5-benzyloxy-cyclohexane-1,2-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(±)-2,3-O-isopropylidene-1,4,5-tri-O-allyl-6-O-benzyl-myo-inositol (98906-37-7) → (1S,2R,3S,4R,5R,6S)-3,4,6-Tris-allyloxy-5-benzyloxy-cyclohexane-1,2-diol (111392-09-7,117708-89-1,117708-90-4,136172-90-2,141040-46-2,141040-49-5)

Guidance literature:

With hydrogenchloride; In methanol; for 30h; Heating;

Reference yield:

(3aR,4S,5S,6S,7S,7aR)-4,5,7-Tris-allyloxy-6-benzyloxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxole (98906-37-7) → (+/-)-1,3,4-Tri-O-allyl-2-O-benzyl-myo-inositol (111392-09-7,117708-89-1,117708-90-4,136172-90-2,141040-46-2,141040-49-5)

Guidance literature:

With hydrogenchloride; In acetone; for 0.25h; Yield given; Heating;

DOI:10.1016/S0008-6215(00)90497-X

Reference yield:

C42H54O12 (140886-97-1,141040-43-9,141040-44-0,141040-45-1) → (1R,2R,3S,4R,5S,6S)-3,4,6-Tris-allyloxy-5-benzyloxy-cyclohexane-1,2-diol (141040-46-2)

Guidance literature:

With sodium hydroxide; In methanol;

DOI:10.1016/S0008-6215(00)90497-X

upstream raw materials:

(±)-2,3-O-isopropylidene-1,4,5-tri-O-allyl-6-O-benzyl-myo-inositol

(+/-)-3,6-di-O-allyl-1,2-O-cyclohexylidene-myo-inositol

(+/-)-3,6-di-O-allyl-4-O-benzyl-1,2-O-cyclohexylidene-myo-inositol

(+/-)-1,2:4,5-di-O-isopropylidene-myo-inositol

Downstream raw materials:

(+)-1,3,4-tri-O-allyl-2,5,6-tri-O-benzyl-myo-inositol

(-)-1D-2,5,6-tri-O-benzyl-myo-inositol

C₄₂H₅₄O₁₂

C₄₂H₅₄O₁₂

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