2-[6-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-hex-1-ynyl]-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

Base Information

• Chemical Name: 2-[6-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-hex-1-ynyl]-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane
• CAS No.: 851786-73-7
• Molecular Formula: C₂₅H₄₁BO₄Si
• Molecular Weight: 444.495
• Mol file: 851786-73-7.mol

Synonyms:2-[6-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-hex-1-ynyl]-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

Chemical Property of 2-[6-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-hex-1-ynyl]-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 2-[6-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-hex-1-ynyl]-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

There total 1 articles about 2-[6-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-hex-1-ynyl]-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C19H29LiO2Si + 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (61676-62-8) → 2-[6-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-hex-1-ynyl]-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane (851786-73-7)

Guidance literature:

DOI:10.1021/ol050542r

Reference yield: 86.0%

(1-benzyloxymethyl-pent-4-enyloxy)-tert-butyl-dimethyl-silane (851786-79-3) + 2-[6-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-hex-1-ynyl]-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane (851786-73-7) → 2-[6-benzyloxy-1-{1-[4-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-butyl]-vinyl}-5-(tert-butyl-dimethyl-silanyloxy)-hex-1-enyl]-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

Guidance literature:

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; at 40 ℃;

DOI:10.1021/ol050542r

Reference yield:

2-[6-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-hex-1-ynyl]-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane (851786-73-7) + oct-1-ene (111-66-0,25068-25-1) → 2-(1-{1-[4-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-butyl]-vinyl}-oct-1-enyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane + 2-(1-{1-[4-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-butyl]-vinyl}-oct-1-enyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

Guidance literature:

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; at 40 ℃; Title compound not separated from byproducts;

DOI:10.1021/ol050542r

upstream raw materials:

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane