Technology Process of CH2CHCH2C(C(O)OCH3)2CHCC6H10
There total 3 articles about CH2CHCH2C(C(O)OCH3)2CHCC6H10 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
dimethyl allylmalonate;
With
sodium hydride;
In
tetrahydrofuran; mineral oil;
at 20 ℃;
for 0.333333h;
1-bromo-3,3-(pentamethylene)-1,2-propadiene;
In
tetrahydrofuran; mineral oil;
at 40 ℃;
for 16h;
DOI:10.1002/anie.201008032
- Guidance literature:
-
dimethyl allylmalonate; 1-bromo-3,3-(pentamethylene)-1,2-propadiene;
With
sodium hydride;
In
tetrahydrofuran;
Inert atmosphere;
Reflux;
With
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine;
In
tetrahydrofuran;
at 23 ℃;
Inert atmosphere;
DOI:10.1002/anie.201501048
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: hydrogen bromide; copper; copper(I) bromide / water; pentane / 20 - 40 °C
2.1: sodium hydride / tetrahydrofuran; mineral oil / 0.33 h / 20 °C
2.2: 16 h / 40 °C
With
hydrogen bromide; copper; sodium hydride; copper(I) bromide;
In
tetrahydrofuran; water; mineral oil; pentane;
DOI:10.1002/anie.201008032
