2-(N,N-diphenylamino)-4,9-dihydro-4,4,9,9-(p-hexoxyphen-yl)-7-formyl-s-indaceno[1,2-b:5,6-b']dithiophene

Base Information

Chemical Name:2-(N,N-diphenylamino)-4,9-dihydro-4,4,9,9-(p-hexoxyphen-yl)-7-formyl-s-indaceno[1,2-b:5,6-b']dithiophene
CAS No.:1187423-23-9
Molecular Formula:C₇₇H₈₃NO₅S₂
Molecular Weight:1166.64
Hs Code.:

Synonyms:2-(N,N-diphenylamino)-4,9-dihydro-4,4,9,9-(p-hexoxyphen-yl)-7-formyl-s-indaceno[1,2-b:5,6-b']dithiophene

Suppliers and Price of 2-(N,N-diphenylamino)-4,9-dihydro-4,4,9,9-(p-hexoxyphen-yl)-7-formyl-s-indaceno[1,2-b:5,6-b']dithiophene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-(N,N-diphenylamino)-4,9-dihydro-4,4,9,9-(p-hexoxyphen-yl)-7-formyl-s-indaceno[1,2-b:5,6-b']dithiophene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-(N,N-diphenylamino)-4,9-dihydro-4,4,9,9-(p-hexoxyphen-yl)-7-formyl-s-indaceno[1,2-b:5,6-b']dithiophene

There total 6 articles about 2-(N,N-diphenylamino)-4,9-dihydro-4,4,9,9-(p-hexoxyphen-yl)-7-formyl-s-indaceno[1,2-b:5,6-b']dithiophene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 1187423-00-2
2-(N,N-diphenylamino)-4,9-dihydro-4,4,9,9-(p-hexoxyphenyl)-s-indaceno[1,2-b:5,6-b']dithiophene

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 1187423-23-9
2-(N,N-diphenylamino)-4,9-dihydro-4,4,9,9-(p-hexoxyphen-yl)-7-formyl-s-indaceno[1,2-b:5,6-b']dithiophene

Guidance literature:: With trichlorophosphate; at 0 ℃;

Reference yield:

: 1187422-97-4
4,9-dihydro-4,4,9,9-(p-hexoxyphenyl)-s-indaceno[1,2-b:5,6-b']dithiophene

: 1187423-23-9
2-(N,N-diphenylamino)-4,9-dihydro-4,4,9,9-(p-hexoxyphen-yl)-7-formyl-s-indaceno[1,2-b:5,6-b']dithiophene

Guidance literature:: Multi-step reaction with 3 steps

1: N-Bromosuccinimide / dichloromethane / 2 h / 20 °C

2: tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate / toluene / 10 h / Reflux

3: trichlorophosphate / 5 h / 0 - 80 °C

With N-Bromosuccinimide; tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate; trichlorophosphate; In dichloromethane; toluene; 3: Vilsmeier-Haack reaction;
DOI:10.1021/jo201730a

Reference yield:

: 1187422-93-0
2,5-bis-(5-trimethylsilanyl-thiophen-2-yl)-terephthalic acid diethyl ester

: 1187423-23-9
2-(N,N-diphenylamino)-4,9-dihydro-4,4,9,9-(p-hexoxyphen-yl)-7-formyl-s-indaceno[1,2-b:5,6-b']dithiophene

Guidance literature:: Multi-step reaction with 5 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 - -50 °C

1.2: 12 h / -50 - 20 °C

2.1: hydrogenchloride; acetic acid / water / 2 h / 80 °C

3.1: N-Bromosuccinimide / dichloromethane / 2 h / 20 °C

4.1: tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate / toluene / 10 h / Reflux

5.1: trichlorophosphate / 5 h / 0 - 80 °C

With hydrogenchloride; N-Bromosuccinimide; n-butyllithium; tri-tert-butyl phosphine; palladium diacetate; acetic acid; sodium t-butanolate; trichlorophosphate; In tetrahydrofuran; hexane; dichloromethane; water; toluene; 5.1: Vilsmeier-Haack reaction;
DOI:10.1021/jo201730a