(S)-6-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-butyl]-tetrahydro-pyran-2-one

Base Information

Chemical Name:(S)-6-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-butyl]-tetrahydro-pyran-2-one
CAS No.:887612-08-0
Molecular Formula:C₂₆H₃₆O₃Si
Molecular Weight:424.656
Hs Code.:

Synonyms:(S)-6-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-butyl]-tetrahydro-pyran-2-one

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Chemical Property of (S)-6-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-butyl]-tetrahydro-pyran-2-one

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Technology Process of (S)-6-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-butyl]-tetrahydro-pyran-2-one

There total 4 articles about (S)-6-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-butyl]-tetrahydro-pyran-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: ((E)-(2S,5S)-5-Benzyloxy-2-methyl-octa-3,7-dienyloxy)-tert-butyl-diphenyl-silane

: 887612-08-0
(S)-6-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-butyl]-tetrahydro-pyran-2-one

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / Cl₂(Cy₃P)(IMes)Ru=CHPh / CH₂Cl₂ / 1.5 h / 40 °C

2: H₂ / Pd/C / ethyl acetate / 24 h

With Cl₂(PCy₃)(N,N'-(Mes)2-imidazolidin-2-yl)Ru=CHC₆H₅; hydrogen; palladium on activated charcoal; In dichloromethane; ethyl acetate;
DOI:10.1021/ja057686l

Reference yield:

: (5S,8S)-9-(tert-Butyl-diphenyl-silanyloxy)-5-hydroxy-8-methyl-nonanoic acid methyl ester

: 887612-08-0
(S)-6-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-butyl]-tetrahydro-pyran-2-one

Guidance literature:: With toluene-4-sulfonic acid; In benzene; at 80 ℃; for 3h;
DOI:10.1021/ja057686l

Reference yield:

: (2E,6E)-(5S,8S)-5-Benzyloxy-9-(tert-butyl-diphenyl-silanyloxy)-8-methyl-nona-2,6-dienoic acid methyl ester

: 887612-08-0
(S)-6-[(S)-4-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-butyl]-tetrahydro-pyran-2-one

Guidance literature:: Multi-step reaction with 2 steps

1: H₂ / Pd/C / ethyl acetate / 24 h

2: pTSA / benzene / 3 h / 80 °C

With hydrogen; toluene-4-sulfonic acid; palladium on activated charcoal; In ethyl acetate; benzene;
DOI:10.1021/ja057686l