ethyl 2,6-dideoxy-6,6,6-trifluoro-3-O-[(1R)-1-phenylethyl]-β-D-arabino-hexopyranoside

Base Information

• Chemical Name: ethyl 2,6-dideoxy-6,6,6-trifluoro-3-O-[(1R)-1-phenylethyl]-β-D-arabino-hexopyranoside
• CAS No.: 261629-67-8
• Molecular Formula: C₁₆H₂₁F₃O₄
• Molecular Weight: 334.336

Synonyms:ethyl 2,6-dideoxy-6,6,6-trifluoro-3-O-[(1R)-1-phenylethyl]-β-D-arabino-hexopyranoside

Chemical Property of ethyl 2,6-dideoxy-6,6,6-trifluoro-3-O-[(1R)-1-phenylethyl]-β-D-arabino-hexopyranoside

Chemical Property:

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Technology Process of ethyl 2,6-dideoxy-6,6,6-trifluoro-3-O-[(1R)-1-phenylethyl]-β-D-arabino-hexopyranoside

There total 1 articles about ethyl 2,6-dideoxy-6,6,6-trifluoro-3-O-[(1R)-1-phenylethyl]-β-D-arabino-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

2-ethoxy-4-[(1R)-1-phenylethoxy]-6-trifluoromethyl-3,4-dihydro-2H-pyran → ethyl 2,6-dideoxy-6,6,6-trifluoro-3-O-[(1R)-1-phenylethyl]-β-D-arabino-hexopyranoside (261629-67-8) + ethyl 2,6-dideoxy-6,6,6-trifluoro-3-O-[(1R)-1-phenylethyl]-β-L-arabino-hexopyranoside

Guidance literature:

2-ethoxy-4-[(1R)-1-phenylethoxy]-6-trifluoromethyl-3,4-dihydro-2H-pyran; With dimethylsulfide borane complex; In dichloromethane; at 0 - 20 ℃; for 17h;

With sodium hydroxide; dihydrogen peroxide; In tetrahydrofuran; methanol; dichloromethane; at 20 ℃; for 5h;

DOI:10.1071/CH99067

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