1-(1-glycero)Dodeca-1,3,5,7,9-pentaene

Base Information

Chemical Name:1-(1-glycero)Dodeca-1,3,5,7,9-pentaene
CAS No.:84000-59-9
Molecular Formula:C₁₅H₂₂O₃
Molecular Weight:250.338
Hs Code.:
Nikkaji Number:J460.223D
ChEMBL ID:CHEMBL486102
Mol file:84000-59-9.mol

Synonyms:1-(1-glycero)dodeca-1,3,5,7,9-pentaene;fecapentaene-12;GDPE

Suppliers and Price of 1-(1-glycero)Dodeca-1,3,5,7,9-pentaene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 1-(1-glycero)Dodeca-1,3,5,7,9-pentaene

Chemical Property:

Vapor Pressure:1.09E-09mmHg at 25°C
Boiling Point:442.5°C at 760 mmHg
Flash Point:221.4°C
PSA：49.69000
Density:1.017g/cm³
LogP:2.50470
XLogP3:2.8
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:9
Exact Mass:250.15689456
Heavy Atom Count:18
Complexity:312

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCC=CC=CC=CC=CC=COCC(CO)O
Isomeric SMILES:CC/C=C/C=C/C=C/C=C/C=C/OCC(CO)O

Technology Process of 1-(1-glycero)Dodeca-1,3,5,7,9-pentaene

There total 14 articles about 1-(1-glycero)Dodeca-1,3,5,7,9-pentaene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 89229-61-8,89300-17-4
(1E,3E,5E,7E,9E)-1-[2,3-Bis-(tert-butyl-dimethyl-silanyloxy)-propoxy]-dodeca-1,3,5,7,9-pentaene

: 84000-59-9,89300-15-2,89300-16-3,91423-46-0,91605-35-5,113775-79-4,116299-52-6,116299-53-7,132074-19-2,132074-20-5,83248-46-8
Fecapentaene-12

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 ℃; for 1h; Yield given;
DOI:10.1016/S0040-4020(01)87909-6

Reference yield:

: 89229-61-8,89300-17-4
(1E,3E,5E,7E,9E)-1-[2,3-Bis-(tert-butyl-dimethyl-silanyloxy)-propoxy]-dodeca-1,3,5,7,9-pentaene

: 84000-59-9,89300-15-2,89300-16-3,91423-46-0,91605-35-5,113775-79-4,116299-52-6,116299-53-7,132074-19-2,132074-20-5,83248-46-8
3-<(1E,3E,7E,9E)-1,3,5,7,9-dodecapentaenyloxy>-1,2-propanediol

Guidance literature:: With tetrabutyl ammonium fluoride; triethylamine; In tetrahydrofuran; at 30 ℃; for 1h;
DOI:10.1016/S0040-4039(00)94111-X

Reference yield:

: 4313-03-5
(2E,4E)-hepta-2,4-dienal

: 84000-59-9,89300-15-2,89300-16-3,91423-46-0,91605-35-5,113775-79-4,116299-52-6,116299-53-7,132074-19-2,132074-20-5,83248-46-8
3-<(1E,3E,7E,9E)-1,3,5,7,9-dodecapentaenyloxy>-1,2-propanediol

Guidance literature:: Multi-step reaction with 5 steps

1: reduction

3: n-BuLi / tetrahydrofuran / 0.5 h / -78 °C

4: 1.) MnO₂ / 1.) hexane, ether, 80 deg C, 3 h 2.) THF, 30 deg C, 30 min.

5: (n-Bu)4N⁽¹⁺⁾*F^(1-), Et₃N / tetrahydrofuran / 1 h / 30 °C

With manganese(IV) oxide; n-butyllithium; tetrabutyl ammonium fluoride; triethylamine; In tetrahydrofuran;
DOI:10.1016/S0040-4039(00)94111-X