Phenylmercuric hydroxide

Base Information

• Chemical Name: Phenylmercuric hydroxide
• CAS No.: 100-57-2
• Molecular Formula: C6H6HgO
• Molecular Weight: 294.703
• Hs Code.: 2852 10 00
• European Community (EC) Number: 202-866-7
• NSC Number: 4773
• UN Number: 1894
• DSSTox Substance ID: DTXSID8059213
• Mol file: 100-57-2.mol

Synonyms:PHENYLMERCURIC HYDROXIDE;Phenylmercury hydroxide;Hydroxyphenylmercury;100-57-2;Mersolite 1;Mercury, hydroxyphenyl-;Phenyl hydroxymercury;Caswell No. 657C;NSC 4773;EINECS 202-866-7;UN1894;UNII-Y38LBL8A8G;EPA Pesticide Chemical Code 066011;BRN 0636144;C6H6HgO;Mercurio, hidroxifenil-;Hydroxyde phnylmercurique;WLN: Q-HG-R;C6-H6-Hg-O;SCHEMBL1310086;DTXSID8059213;NSC4773;NA1894;LS-89806;Phenylmercuric hydroxide [UN1894] [Poison];Phenylmercuric hydroxide [UN1894] [Poison]

Chemical Property of Phenylmercuric hydroxide

Chemical Property:

• Appearance/Colour: solid
• Melting Point: 190 °C
• Boiling Point: 126.5°C
• PSA: 20.23000
• LogP: 0.68190
• Storage Temp.: Store below +30°C.
• Solubility.: 50g/l
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 297.020333
• Heavy Atom Count: 8
• Complexity: 50.5
• Transport DOT Label: Poison

Purity/Quality:

98%min ^*data from raw suppliers

Phenylmercury hydroxide for synthesis. CAS 100-57-2, EC Number 202-866-7, chemical formula C H HgOH., for synthesis ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T+,N
• Hazard Codes: T+,N,T
• Statements: 26/27/28-33-50/53-48/24/25-34-25
• Safety Statements: 13-28-36-45-60-61-37-24/25-23

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Organic Compounds
• Canonical SMILES: C1=CC=C(C=C1)[Hg].O

Technology Process of Phenylmercuric hydroxide

There total 2 articles about Phenylmercuric hydroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

8-quinolinol (148-24-3,24804-14-6) + phenylmercury cation → 8-(Phenylmercurioxy)-chinolin (124218-66-2) + phenylmercuric hydroxide (100-57-2)

Guidance literature:

With NaH₂PO₄; Na₂HPO₄; H₂O; In water; benzene; NaH2PO4, Na2HPO4, and PhHg(1+) solns. dild. with deionized water, 8-quinolinol soln. in C6H6 added, shaken for 30 min; org. layer analyzed by means of spectrophotometry;

DOI:10.1246/bcsj.57.2271

Reference yield:

sodium tetraphenyl borate (143-66-8) + mercury(II) hydroxide → phenylmercuric hydroxide (100-57-2) + diphenylmercury(II) (587-85-9,1337-09-3)

Guidance literature:

With acetone; byproducts: NaOH, H3BO3;

Reference yield: 95.0%

4-fluoro-2-bromobenzenesulfonanilide (1179736-70-9) + phenylmercuric hydroxide (100-57-2) → phenylmercury(4'-fluoro-2'-bromobenzenesulfonanilide)

Guidance literature:

In methanol; addn. of a filtered hot soln. of Hg-compd. in CH3OH to a hot soln. of sulfonanilide in CH3OH; removal of solvent, recrystn. from CH3OH; elem. anal.;

DOI:10.1007/BF00948068

upstream raw materials:

sodium tetraphenyl borate

8-quinolinol

Downstream raw materials:

PhHgSC₆H₄-2-NMe₂

1-(HgC₆H₅)-2-(C₆H₅)-1.2-C₂B₁₀H₁₀

1-(HgC₆H₅)-2-(CH₃)-8.9.10.12-Br₄-1.2-C₂B₁₀H₆

N-phenylmercuro-4-fluorobenzenesulfonanilide

Refernces