methyl 4-O-benzyl-2,6-dideoxy-6-C-methyl-3-O-p-nitrobenzoyl-α-D-arabino-hexopyranoside

Base Information

Chemical Name:methyl 4-O-benzyl-2,6-dideoxy-6-C-methyl-3-O-p-nitrobenzoyl-α-D-arabino-hexopyranoside
CAS No.:872182-81-5
Molecular Formula:C₂₂H₂₅NO₇
Molecular Weight:415.443
Hs Code.:

Synonyms:methyl 4-O-benzyl-2,6-dideoxy-6-C-methyl-3-O-p-nitrobenzoyl-α-D-arabino-hexopyranoside

Suppliers and Price of methyl 4-O-benzyl-2,6-dideoxy-6-C-methyl-3-O-p-nitrobenzoyl-α-D-arabino-hexopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 2 raw suppliers

Chemical Property of methyl 4-O-benzyl-2,6-dideoxy-6-C-methyl-3-O-p-nitrobenzoyl-α-D-arabino-hexopyranoside

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of methyl 4-O-benzyl-2,6-dideoxy-6-C-methyl-3-O-p-nitrobenzoyl-α-D-arabino-hexopyranoside

There total 4 articles about methyl 4-O-benzyl-2,6-dideoxy-6-C-methyl-3-O-p-nitrobenzoyl-α-D-arabino-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 872182-68-8
methyl 4-O-benzyl-2,6-dideoxy-6-C-methyl-α-D-ribo-hexopyranoside

: 62-23-7
4-nitro-benzoic acid

: 872182-81-5
methyl 4-O-benzyl-2,6-dideoxy-6-C-methyl-3-O-p-nitrobenzoyl-α-D-arabino-hexopyranoside

Guidance literature:: With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; at 20 ℃; for 12h;
DOI:10.1139/v05-095

Reference yield:

: 872182-66-6
methyl 4-O-benzyl-2-deoxy-α-D-ribo-hexopyranoside

: 872182-81-5
methyl 4-O-benzyl-2,6-dideoxy-6-C-methyl-3-O-p-nitrobenzoyl-α-D-arabino-hexopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1.1: 80 percent / pyridine / CH₂Cl₂ / 16 h / 20 °C

2.1: copper(I) iodide / diethyl ether / 0.33 h / -5 °C

2.2: 89 percent / diethyl ether / 4 h / -78 - 20 °C

3.1: 78 percent / triphenylphosphine; diisopropyl azodicarboxylate / tetrahydrofuran / 12 h / 20 °C

With pyridine; copper(l) iodide; di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; diethyl ether; dichloromethane; 3.1: Mitsunobu reaction;
DOI:10.1139/v05-095

Reference yield:

: 872182-67-7
methyl 4-O-benzyl-2-deoxy-6-O-p-tolylsulofnyl-α-D-ribo-hexopyranoside

: 872182-81-5
methyl 4-O-benzyl-2,6-dideoxy-6-C-methyl-3-O-p-nitrobenzoyl-α-D-arabino-hexopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1.1: copper(I) iodide / diethyl ether / 0.33 h / -5 °C

1.2: 89 percent / diethyl ether / 4 h / -78 - 20 °C

2.1: 78 percent / triphenylphosphine; diisopropyl azodicarboxylate / tetrahydrofuran / 12 h / 20 °C

With copper(l) iodide; di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; diethyl ether; 2.1: Mitsunobu reaction;
DOI:10.1139/v05-095