[Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)]

Base Information

• Chemical Name: [Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)]
• CAS No.: 317322-17-1
• Molecular Formula: C₂₉H₄₁GaN₂
• Molecular Weight: 487.381
• Mol file: 317322-17-1.mol

Synonyms:[Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)]

Chemical Property of [Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)]

There total 10 articles about [Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

gallium(I) iodide + Dipp2nacnacLi*Et2O (334719-92-5,872515-36-1) → [Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)] (317322-17-1) + Dipp2nacnacGaI2 (349545-06-8)

Guidance literature:

In toluene; ligand was added to GaI in toluene with cooling in ice-acetone bath, warmed to room temp. overnight under inert atm.; vol. was reduced, placed in -20°C for 48 h, sepd., pumped to dryness, washed with hexane, recrystd. from hot toluene, cooled in -20°C freezer; elem. anal.;

DOI:10.1021/ic001311d

Reference yield:

[{N,N,N',N'-tetramethylethylenediamine}Al(H)(H)Ga{{HC(C(CH3)N(2,6-iPr2-C6H3))2}}][B(C6H3-3,5-Me2)4] → [Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)] (317322-17-1)

Guidance literature:

[{N,N,N',N'-tetramethylethylenediamine}Al(H)(H)Ga{{HC(C(CH₃)N(2,6-iPr₂-C₆H₃))2}}][B(C₆H₃-3,5-Me₂)₄]; With 1,3,4,5-Tetramethylimidazol-2-yliden; In benzene-d6; at 20 ℃; for 0.25h; Schlenk technique; Inert atmosphere; Glovebox;

In benzene-d6; at 20 - 60 ℃; for 25h;

DOI:10.1039/d1cc03706d

Reference yield:

N,N′-bis(2,6-diisopropylphenyl)pentane-2,4-diimine (210832-39-6) → [Ga(2-((2,6-diisoproylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene)] (317322-17-1)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium amide / toluene / 80 °C / Inert atmosphere; Schlenk technique

2: toluene / 72 h / 90 °C / Schlenk technique; Green chemistry

With sodium amide; In toluene;

DOI:10.1039/d0dt01342k

upstream raw materials:

Dipp₂nacnacLi*Et₂O

[Ga₂C₅Me₅][B(C₆H₃(CF₃)2)4]*fluorobenzene

gallium

Li(2,6-iPr₂C₆H₃)NC(Me)CHC(Me)N(2,6-iPr₂C₆H₃)

Downstream raw materials:

ZnCl(tetrahydrofuran)2(GaCl(2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]-2-pentene))