C₁₄H₁₆O₅

Base Information

Chemical Name:C₁₄H₁₆O₅
CAS No.:1301166-58-4
Molecular Formula:C₁₄H₁₆O₅
Molecular Weight:264.278
Hs Code.:

C<sub>14</sub>H<sub>16</sub>O<sub>5</sub>

Synonyms:C₁₄H₁₆O₅

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Chemical Property of C₁₄H₁₆O₅

Chemical Property:

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Technology Process of C₁₄H₁₆O₅

There total 10 articles about C₁₄H₁₆O₅ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 1301166-57-3
C₂₀H₂₈O₇

: 1301166-58-4
C₁₄H₁₆O₅

Guidance literature:: With cerium(III) chloride heptahydrate; In acetonitrile; for 12h; Reflux;
DOI:10.1016/j.tetlet.2011.02.025

Reference yield:

: 1301166-51-7
C₁₀H₁₈O₅

: 1301166-58-4
C₁₄H₁₆O₅

Guidance literature:: Multi-step reaction with 7 steps

1.1: Nitrosobenzene; D-Prolin / dimethyl sulfoxide

1.2: 0.5 h

2.1: 1H-imidazole / dichloromethane / 1 h

3.1: tetra-(n-butyl)ammonium iodide; sodium hydride / tetrahydrofuran / 2 h / 0 - 20 °C

4.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0 - 20 °C

5.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dichloromethane; dimethyl sulfoxide / 3 h / 20 °C

6.1: sodium hydride / tetrahydrofuran

7.1: cerium(III) chloride heptahydrate / acetonitrile / 12 h / Reflux

With 1H-imidazole; cerium(III) chloride heptahydrate; tetrabutyl ammonium fluoride; tetra-(n-butyl)ammonium iodide; sodium hydride; Nitrosobenzene; D-Prolin; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; dichloromethane; dimethyl sulfoxide; acetonitrile; 1.1: MacMillan α-hydroxylation / 1.2: MacMillan α-hydroxylation / 1.3: MacMillan α-hydroxylation / 6.1: Still-Gennari cis-ofefination;
DOI:10.1016/j.tetlet.2011.02.025

Reference yield:

: C₁₁H₂₂O₆

: 1301166-58-4
C₁₄H₁₆O₅

Guidance literature:: Multi-step reaction with 8 steps

1.1: sodium periodate / 2 h / 20 °C

2.1: Nitrosobenzene; D-Prolin / dimethyl sulfoxide

2.2: 0.5 h

3.1: 1H-imidazole / dichloromethane / 1 h

4.1: tetra-(n-butyl)ammonium iodide; sodium hydride / tetrahydrofuran / 2 h / 0 - 20 °C

5.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0 - 20 °C

6.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dichloromethane; dimethyl sulfoxide / 3 h / 20 °C

7.1: sodium hydride / tetrahydrofuran

8.1: cerium(III) chloride heptahydrate / acetonitrile / 12 h / Reflux

With 1H-imidazole; sodium periodate; cerium(III) chloride heptahydrate; tetrabutyl ammonium fluoride; tetra-(n-butyl)ammonium iodide; sodium hydride; Nitrosobenzene; D-Prolin; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; dichloromethane; dimethyl sulfoxide; acetonitrile; 2.1: MacMillan α-hydroxylation / 2.2: MacMillan α-hydroxylation / 2.3: MacMillan α-hydroxylation / 7.1: Still-Gennari cis-ofefination;
DOI:10.1016/j.tetlet.2011.02.025