C₅₆H₉₂O₇Si₃

Base Information

• Chemical Name: C₅₆H₉₂O₇Si₃
• CAS No.: 955030-37-2
• Molecular Formula: C₅₆H₉₂O₇Si₃
• Molecular Weight: 961.599
• Mol file: 955030-37-2.mol

Synonyms:C₅₆H₉₂O₇Si₃

Chemical Property of C₅₆H₉₂O₇Si₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₅₆H₉₂O₇Si₃

There total 18 articles about C₅₆H₉₂O₇Si₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

C27H56O4Si2 (955030-32-7) + C31H40O3Si (955030-23-6) → C60H76O6Si2 + C56H92O7Si3 (955030-37-2)

Guidance literature:

1,3-bis(mesityl)imidazolidine-2-yl[Cl₂Ru(PCy₃)=CHPh]; In dichloromethane; Heating;

DOI:10.1016/j.tetlet.2007.07.156

Reference yield:

C17H22O3 (955030-27-0) → C56H92O7Si3 (955030-37-2)

Guidance literature:

Multi-step reaction with 10 steps

1: 92 percent / TiCl₄; (-)-Sparteine / CH₂Cl₂ / 0 °C

2: 90 percent / imidazole / dimethylformamide

3: 75 percent / NaBH₄ / tetrahydrofuran; H₂O

4: 85 percent / TEMPO; IBDA / CH₂Cl₂

5: 90 percent / TiCl₄; (-)-Sparteine / CH₂Cl₂ / 0 °C

6: 90 percent / NaBH₄ / tetrahydrofuran; H₂O

7: 85 percent / CSA / CH₂Cl₂

8: 90 percent / DIBAL-H / CH₂Cl₂ / 0 °C

9: 15 percent / DDQ / CH₂Cl₂; H₂O

10: 60 percent / 1,3-bis(mesityl)imidazolidine-2-yl[Cl₂Ru(PCy₃)=CHPh] / CH₂Cl₂ / Heating

With 1H-imidazole; 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium tetrahydroborate; camphor-10-sulfonic acid; titanium tetrachloride; diisobutylaluminium hydride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; (-)-sparteine; 1,3-bis(mesityl)imidazolidine-2-yl[Cl₂Ru(PCy₃)=CHPh]; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; 1: Crimmins asymmetric aldol reaction / 5: Crimmins asymmetric aldol reaction;

DOI:10.1016/j.tetlet.2007.07.156

Reference yield:

C26H42O4Si (955030-29-2) → C56H92O7Si3 (955030-37-2)

Guidance literature:

Multi-step reaction with 6 steps

1: 90 percent / TiCl₄; (-)-Sparteine / CH₂Cl₂ / 0 °C

2: 90 percent / NaBH₄ / tetrahydrofuran; H₂O

3: 85 percent / CSA / CH₂Cl₂

4: 90 percent / DIBAL-H / CH₂Cl₂ / 0 °C

5: 15 percent / DDQ / CH₂Cl₂; H₂O

6: 60 percent / 1,3-bis(mesityl)imidazolidine-2-yl[Cl₂Ru(PCy₃)=CHPh] / CH₂Cl₂ / Heating

With sodium tetrahydroborate; camphor-10-sulfonic acid; titanium tetrachloride; diisobutylaluminium hydride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; (-)-sparteine; 1,3-bis(mesityl)imidazolidine-2-yl[Cl₂Ru(PCy₃)=CHPh]; In tetrahydrofuran; dichloromethane; water; 1: Crimmins asymmetric aldol reaction;

DOI:10.1016/j.tetlet.2007.07.156

upstream raw materials:

C₂₇H₅₆O₄Si₂

C₃₁H₄₀O₃Si

C₁₇H₂₄O₃

C₁₇H₂₂O₃