(+)-<(R)-<(benzyloxy)methyl>(tert-butyl)methylsilyl> (R)-1-phenylethyl ether

Base Information

Chemical Name:(+)-<(R)-<(benzyloxy)methyl>(tert-butyl)methylsilyl> (R)-1-phenylethyl ether
CAS No.:175022-34-1
Molecular Formula:C₂₁H₃₀O₂Si
Molecular Weight:342.554
Hs Code.:

Synonyms:(+)-<(R)-<(benzyloxy)methyl>(tert-butyl)methylsilyl> (R)-1-phenylethyl ether

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Chemical Property of (+)-<(R)-<(benzyloxy)methyl>(tert-butyl)methylsilyl> (R)-1-phenylethyl ether

Chemical Property:

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Technology Process of (+)-<(R)-<(benzyloxy)methyl>(tert-butyl)methylsilyl> (R)-1-phenylethyl ether

There total 4 articles about (+)-<(R)-<(benzyloxy)methyl>(tert-butyl)methylsilyl> (R)-1-phenylethyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 175272-28-3
(SiR,1R)-(+)-1-<<(benzyloxy)methyl>(tert-butyl)methylsilyl>-1-phenylethanol

: 175022-34-1
(+)-<(R)-<(benzyloxy)methyl>(tert-butyl)methylsilyl> (R)-1-phenylethyl ether

Guidance literature:: With potassium hydride; In tetrahydrofuran; at 23 ℃; for 0.5h;
DOI:10.1016/0957-4166(95)00422-X

Reference yield:

: 138380-12-8
<<(benzyloxy)methyl>(tert-butyl)methylsilyl> methyl ketone

: 175022-34-1
(+)-<(R)-<(benzyloxy)methyl>(tert-butyl)methylsilyl> (R)-1-phenylethyl ether

Guidance literature:: Multi-step reaction with 4 steps

1: Tris buffer (pH=7.5), glucose, CaCl₂ / 37 °C / Trigonopsis variabilis (DSM 70714)

2: 1.) oxalyl chloride, DMSO, 2.) triethylamine / 1.) CH₂Cl₂, -60 deg C, 15 min, 2.) CH₂Cl₂

3: 86 percent / pentane; hexane / 1 h / -100 °C

4: 98 percent / KH / tetrahydrofuran / 0.5 h / 23 °C

With oxalyl dichloride; D-glucose; Tris buffer; potassium hydride; dimethyl sulfoxide; triethylamine; calcium chloride; In tetrahydrofuran; hexane; pentane;
DOI:10.1016/0957-4166(95)00422-X

Reference yield:

: (R)-1-((R)-Benzyloxymethyl-tert-butyl-methyl-silanyl)-ethanol

: 175022-34-1
(+)-<(R)-<(benzyloxy)methyl>(tert-butyl)methylsilyl> (R)-1-phenylethyl ether

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) oxalyl chloride, DMSO, 2.) triethylamine / 1.) CH₂Cl₂, -60 deg C, 15 min, 2.) CH₂Cl₂

2: 86 percent / pentane; hexane / 1 h / -100 °C

3: 98 percent / KH / tetrahydrofuran / 0.5 h / 23 °C

With oxalyl dichloride; potassium hydride; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; hexane; pentane;
DOI:10.1016/0957-4166(95)00422-X