Ru(C≡CC≡CH)(dppe)Cp*

Base Information

Chemical Name:Ru(C≡CC≡CH)(dppe)Cp*
CAS No.:649720-49-0
Molecular Formula:C₄₀H₄₀P₂Ru
Molecular Weight:683.775
Hs Code.:

Synonyms:Ru(C≡CC≡CH)(dppe)Cp*

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Chemical Property of Ru(C≡CC≡CH)(dppe)Cp*

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Technology Process of Ru(C≡CC≡CH)(dppe)Cp*

There total 1 articles about Ru(C≡CC≡CH)(dppe)Cp* which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 717110-27-5
Ru(C≡CC≡CSiMe₃)(dppe)Cp*

: 649720-49-0
Ru(C≡CC≡CH)(dppe)Cp*

Guidance literature:: With Bu₄NF; In tetrahydrofuran; under Ar atm. Ru(CCCCSiMe3)(dppe)Cp* and Bu4NF in THF were stirred at room temp. for 24 h; solvent was removed in vacuo, residue was extd. with hot hexane, filtered,and concd., ppt. was dried; elem. anal.;
DOI:10.1039/b316297b

Reference yield: 98.0%

: 14243-64-2
(triphenylphosphine)gold(I) chloride

: 649720-49-0
Ru(C≡CC≡CH)(dppe)Cp*

: [Ru(III){CCCCAu(PPh₃)}(dppe)Cp*]

Guidance literature:: With MeONa; In methanol; under Ar atm. to soln. MeONa in MeOH AuCl(PPh3) was added followed by Ru(CCCCH)(dppe)Cp*, 1 h at 0°C; ppt. was filtered, washed with cold MeOH and hexane and dried;
DOI:10.1039/b316297b

Reference yield: 93.0%

: 649720-49-0
Ru(C≡CC≡CH)(dppe)Cp*

: [Ag2(μ-bis(diphenylphosphino)methane)2(MeCN)2][BF4]2

: [{Ag₃(μ-dppm)₃}{μ₃-C≡CC≡C[Ru(dppe)Cp*]}](BF₄)₂

Guidance literature:: Ru(C≡CC≡CH)(dppe)Cp*; With n-butyllithium; In tetrahydrofuran; hexane; Inert atmosphere;

[Ag2(μ-bis(diphenylphosphino)methane)2(MeCN)2][BF4]2; In tetrahydrofuran; hexane; Inert atmosphere;
DOI:10.1016/j.ica.2016.09.017