Technology Process of C9H21Al
There total 1 articles about C9H21Al which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
bis(η(5)-[1-neomenthylindenyl])zirconium dichloride;
In
dichloromethane;
at 22 ℃;
for 20h;
optical yield given as %ee;
enantioselective reaction;
Inert atmosphere;
DOI:10.1016/j.tetasy.2010.01.001
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: N,N-dimethyl-formamide / 2 h / 70 °C / Inert atmosphere
2.1: dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(ll); diisobutylaluminium hydride / tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere
2.2: 0 - 23 °C / Inert atmosphere
3.1: trimethylaluminum; bis(1-(-)-neomenthylindenyl)zirconium dichloride / dichloromethane / 23 °C / Inert atmosphere
3.2: 6 h / 0 - 20 °C
4.1: 4-methylmorpholine N-oxide; tetrapropylammonium perruthennate / acetonitrile / 20 °C
5.1: N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate / dichloromethane / 0 - 20 °C / Inert atmosphere
With
tetrapropylammonium perruthennate; bis(1-(-)-neomenthylindenyl)zirconium dichloride; dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(ll); trimethylaluminum; diisobutylaluminium hydride; 4-methylmorpholine N-oxide; N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate;
In
tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/acs.orglett.8b04050
