2-phenyl-2-tributylstannyl-1,3-dithiane

Base Information

Chemical Name:2-phenyl-2-tributylstannyl-1,3-dithiane
CAS No.:106431-20-3
Molecular Formula:C₂₂H₃₈S₂Sn
Molecular Weight:485.386
Hs Code.:

Synonyms:2-phenyl-2-tributylstannyl-1,3-dithiane

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Chemical Property of 2-phenyl-2-tributylstannyl-1,3-dithiane

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Technology Process of 2-phenyl-2-tributylstannyl-1,3-dithiane

There total 1 articles about 2-phenyl-2-tributylstannyl-1,3-dithiane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 5425-44-5
2-Phenyl-[1,3]dithiane

: 1461-22-9
tributyltin chloride

: 106431-20-3
2-phenyl-2-tributylstannyl-1,3-dithiane

Guidance literature:: With n-butyllithium; In tetrahydrofuran; dropwise addn. of 55mmol n-BuLi in hexane to a soln. of 50mmol 1.3-dithiane in 125ml dry THF (N2), warming to 0°C after 3h at -78°C, cooling to -78°C, addn. of 50mmol Sn-compound, stirring for 3h at -78°C, 12h at 25°C;; addn. of about 10g solid CO2, addn. of 200ml H2O, removal of THF by distn., extractn. of remaining aq. suspension with CH2Cl2, shaking extract with 5% aq. K2CO3-soln., washing, drying (MgSO4), evapn., distn. (168°C/0.004mm); (1)H-, (13)C-NMR, MS;;
DOI:10.1016/0022-328X(86)80130-9

Reference yield: 92.0%

: 13735-81-4
1-styrenyloxytrimethylsilane

: 106431-20-3
2-phenyl-2-tributylstannyl-1,3-dithiane

: 97684-11-2
1-phenyl-2-(2-phenyl-1,3-dithian-2-yl)ethan-1-one

Guidance literature:: With ferrocenium hexafluorophosphate; 4 A molecular sieve; In acetonitrile; Ambient temperature;
DOI:10.1246/cl.1992.1229

Reference yield: 78.0%

: 68081-15-2
1-tert-butyldimethylsilyloxycyclopentene

: 106431-20-3
2-phenyl-2-tributylstannyl-1,3-dithiane

: 2-(2-oxocylopentyl)-2-phenyl-1,3-dithiane

Guidance literature:: With ferrocenium hexafluorophosphate; 4 A molecular sieve; In acetonitrile; Ambient temperature;
DOI:10.1246/bcsj.66.2995