C₂₅H₃₁IO₄Si

Base Information

Chemical Name:C₂₅H₃₁IO₄Si
CAS No.:1612775-39-9
Molecular Formula:C₂₅H₃₁IO₄Si
Molecular Weight:550.509
Hs Code.:

C<sub>25</sub>H<sub>31</sub>IO<sub>4</sub>Si

Synonyms:C₂₅H₃₁IO₄Si

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Chemical Property of C₂₅H₃₁IO₄Si

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Technology Process of C₂₅H₃₁IO₄Si

There total 5 articles about C₂₅H₃₁IO₄Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 1612775-38-8
C₂₇H₃₇NO₃Si

: 1612775-39-9
C₂₅H₃₁IO₄Si

Guidance literature:: With iodine; In tetrahydrofuran; water; at 0 ℃; for 11h; stereoselective reaction; Inert atmosphere;
DOI:10.1021/ol501446w

Reference yield:

: 1612775-35-5
C₂₄H₃₀O₄Si

: 1612775-39-9
C₂₅H₃₁IO₄Si

Guidance literature:: Multi-step reaction with 4 steps

1.1: trimethylaluminum / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

1.2: 1.5 h / 0 - 20 °C / Inert atmosphere

2.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 2.5 h / 20 °C / Inert atmosphere

3.1: potassium tert-butylate / tetrahydrofuran / 1.25 h / 0 °C / Inert atmosphere

3.2: 2 h / 0 °C / Inert atmosphere

4.1: iodine / water; tetrahydrofuran / 11 h / 0 °C / Inert atmosphere

With potassium tert-butylate; iodine; trimethylaluminum; sodium hydrogencarbonate; Dess-Martin periodane; In tetrahydrofuran; hexane; dichloromethane; water; 3.1: |Wittig Olefination / 3.2: |Wittig Olefination;
DOI:10.1021/ol501446w

Reference yield:

: 1612775-34-4
C₃₁H₃₄O₆SSi

: 1612775-39-9
C₂₅H₃₁IO₄Si

Guidance literature:: Multi-step reaction with 5 steps

1.1: tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) / toluene / 0.5 h / Inert atmosphere; Reflux

2.1: trimethylaluminum / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

2.2: 1.5 h / 0 - 20 °C / Inert atmosphere

3.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 2.5 h / 20 °C / Inert atmosphere

4.1: potassium tert-butylate / tetrahydrofuran / 1.25 h / 0 °C / Inert atmosphere

4.2: 2 h / 0 °C / Inert atmosphere

5.1: iodine / water; tetrahydrofuran / 11 h / 0 °C / Inert atmosphere

With 2,2'-azobis(isobutyronitrile); potassium tert-butylate; iodine; trimethylaluminum; tri-n-butyl-tin hydride; sodium hydrogencarbonate; Dess-Martin periodane; In tetrahydrofuran; hexane; dichloromethane; water; toluene; 1.1: |Barton-McCombie Deoxygenation / 4.1: |Wittig Olefination / 4.2: |Wittig Olefination;
DOI:10.1021/ol501446w