dicarbonyl(1-5-η-6-n-butylcycloheptadienylium)(triphenyl phosphite)iron hexafluorophosphate

Base Information

Chemical Name:dicarbonyl(1-5-η-6-n-butylcycloheptadienylium)(triphenyl phosphite)iron hexafluorophosphate
CAS No.:91550-79-7
Molecular Formula:C₃₁H₃₂FeO₅P*F₆P
Molecular Weight:716.377
Hs Code.:

Synonyms:dicarbonyl(1-5-η-6-n-butylcycloheptadienylium)(triphenyl phosphite)iron hexafluorophosphate

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Chemical Property of dicarbonyl(1-5-η-6-n-butylcycloheptadienylium)(triphenyl phosphite)iron hexafluorophosphate

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Technology Process of dicarbonyl(1-5-η-6-n-butylcycloheptadienylium)(triphenyl phosphite)iron hexafluorophosphate

There total 1 articles about dicarbonyl(1-5-η-6-n-butylcycloheptadienylium)(triphenyl phosphite)iron hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: C₇H₉(C₄H₉)Fe(CO)2P(OC₆H₅)3

: 437-17-2
tritylium hexafluorophosphate

: 91550-79-7
dicarbonyl(1-5-η-6-n-butylcycloheptadienylium)(triphenyl phosphite)iron hexafluorophosphate

Guidance literature:: In dichloromethane; Ph3CPF6 dissolved in min. vol. of dry CH2Cl2, Fe complex added, heated at reflux temp. under N2 for 19 h; pptd. by pouring mixt. into wet ether, collected by filtration, washed with wet ether; elem. anal.;
DOI:10.1021/ja00332a050

Reference yield: 91.0%

: 91550-79-7
dicarbonyl(1-5-η-6-n-butylcycloheptadienylium)(triphenyl phosphite)iron hexafluorophosphate

: 18424-76-5
sodiodimethylmalonate

: 91550-83-3
dicarbonyl[dimethyl (2-5-η-6-n-butyl-2,4-cycloheptadienyl)malonate](triphenyl phosphite)iron

Guidance literature:: In not given; by procedure of Pearson, A. J. J. Chem. Soc., Perkin Trans. 1 1977, 2069; purifn. by preparative TLC;
DOI:10.1021/ja00332a050

Reference yield: 68.0%

: 91550-79-7
dicarbonyl(1-5-η-6-n-butylcycloheptadienylium)(triphenyl phosphite)iron hexafluorophosphate

: 917-54-4
methyllithium

: 91550-80-0
dicarbonyl(1-4-η-5-n-butyl-7-methyl-1,3-cycloheptadiene)(triphenyl phosphite)iron

: 91550-85-5
(C₇H₈(CH₃)C₄H₉)Fe(CO)2P(OC₆H₅)3

Guidance literature:: In dichloromethane; Fe complex stirred in dry CH2Cl2 soln. under N2 at -78°C while the alkyllithium reagent (1.1-1.2 equiv) added dropwise, after 15 min excess lithium reagent quenched by dropwise addn. of MeOH, allowed to warm to room temp.; dild. with CH2Cl2, washed with water, dried (MgSO4), evapd., purified by preparative TLC;
DOI:10.1021/ja00332a050