(2R,3S,4R)-2-acetoxy-3-(acryloyloxy)-4-(4-methoxybenzyloxy)hex-5-enyl benzoate

Base Information

Chemical Name:(2R,3S,4R)-2-acetoxy-3-(acryloyloxy)-4-(4-methoxybenzyloxy)hex-5-enyl benzoate
CAS No.:1308247-30-4
Molecular Formula:C₂₆H₂₈O₈
Molecular Weight:468.504
Hs Code.:

Synonyms:(2R,3S,4R)-2-acetoxy-3-(acryloyloxy)-4-(4-methoxybenzyloxy)hex-5-enyl benzoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R,3S,4R)-2-acetoxy-3-(acryloyloxy)-4-(4-methoxybenzyloxy)hex-5-enyl benzoate

Chemical Property:

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Technology Process of (2R,3S,4R)-2-acetoxy-3-(acryloyloxy)-4-(4-methoxybenzyloxy)hex-5-enyl benzoate

There total 8 articles about (2R,3S,4R)-2-acetoxy-3-(acryloyloxy)-4-(4-methoxybenzyloxy)hex-5-enyl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₂₄H₂₆O₇

: 108-24-7
acetic anhydride

: 1308247-30-4
(2R,3S,4R)-2-acetoxy-3-(acryloyloxy)-4-(4-methoxybenzyloxy)hex-5-enyl benzoate

Guidance literature:: In dichloromethane; at 0 - 20 ℃;
DOI:10.1016/j.tet.2011.03.107

Reference yield:

: 1308247-23-5
(1S,2R)-1-(tert-butyldimethylsilyloxy)-1-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-2-ol

: 1308247-30-4
(2R,3S,4R)-2-acetoxy-3-(acryloyloxy)-4-(4-methoxybenzyloxy)hex-5-enyl benzoate

Guidance literature:: Multi-step reaction with 6 steps

1: sodium hydride / tetrahydrofuran / 0 - 20 °C

2: tetrabutyl ammonium fluoride / tetrahydrofuran / 0 - 20 °C

3: triethylamine / dichloromethane / 0 - 20 °C

4: DOWEX-50 resin H⁽¹⁺⁾-form / methanol / 6 h / 20 °C

5: pyridine / dichloromethane / 3 h / 0 °C

6: dichloromethane / 0 - 20 °C

With pyridine; tetrabutyl ammonium fluoride; sodium hydride; triethylamine; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1016/j.tet.2011.03.107

Reference yield:

: 1308247-25-7
(1S,2R)-1-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-(4-methoxybenzyloxy)but-3-enyl acrylate

: 1308247-30-4
(2R,3S,4R)-2-acetoxy-3-(acryloyloxy)-4-(4-methoxybenzyloxy)hex-5-enyl benzoate

Guidance literature:: Multi-step reaction with 3 steps

1: DOWEX-50 resin H⁽¹⁺⁾-form / methanol / 6 h / 20 °C

2: pyridine / dichloromethane / 3 h / 0 °C

3: dichloromethane / 0 - 20 °C

With pyridine; In methanol; dichloromethane;
DOI:10.1016/j.tet.2011.03.107