Technology Process of C39H48O8Si
There total 6 articles about C39H48O8Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C26H24O7;
With
dicyclohexylboron chloride; triethylamine;
In
diethyl ether;
at 0 ℃;
for 2h;
(R)-3-Methyl-6-triethylsilanyl-hex-5-ynal;
With
phosphate buffer; dihydrogen peroxide;
In
methanol; diethyl ether; water;
at -78 - 20 ℃;
pH=7;
DOI:10.1016/j.tet.2006.01.112
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: 93 percent / triethylamine; 4-(dimethylamino)pyridine / CH2Cl2 / 1.5 h
2.1: 58 percent / H2 / Pd-BaSO4 / ethyl acetate / 6 h / 760 Torr
3.1: 87 percent / NMO; TPAP; molecular sieves 4 Angstroem / CH2Cl2 / 0.5 h
4.1: dicyclohexylchloroborane; triethylamine / diethyl ether / 2 h / 0 °C
4.2: 69 percent / H2O2; phosphate buffer / diethyl ether; methanol; H2O / -78 - 20 °C / pH 7
With
dmap; N-methyl-2-indolinone; tetrapropylammonium perruthennate; 4 A molecular sieve; dicyclohexylboron chloride; hydrogen; triethylamine;
palladium on barium sulfate;
In
diethyl ether; dichloromethane; ethyl acetate;
DOI:10.1016/j.tet.2006.01.112
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: 58 percent / H2 / Pd-BaSO4 / ethyl acetate / 6 h / 760 Torr
2.1: 87 percent / NMO; TPAP; molecular sieves 4 Angstroem / CH2Cl2 / 0.5 h
3.1: dicyclohexylchloroborane; triethylamine / diethyl ether / 2 h / 0 °C
3.2: 69 percent / H2O2; phosphate buffer / diethyl ether; methanol; H2O / -78 - 20 °C / pH 7
With
N-methyl-2-indolinone; tetrapropylammonium perruthennate; 4 A molecular sieve; dicyclohexylboron chloride; hydrogen; triethylamine;
palladium on barium sulfate;
In
diethyl ether; dichloromethane; ethyl acetate;
DOI:10.1016/j.tet.2006.01.112
