CpFe(dppe)(CCC₆H₄-4-Me)

Base Information

Chemical Name:CpFe(dppe)(CCC₆H₄-4-Me)
CAS No.:1130297-85-6
Molecular Formula:C₄₀H₃₆FeP₂
Molecular Weight:634.52
Hs Code.:

CpFe(dppe)(CCC<sub>6</sub>H<sub>4</sub>-4-Me)

Synonyms:CpFe(dppe)(CCC₆H₄-4-Me)

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Chemical Property of CpFe(dppe)(CCC₆H₄-4-Me)

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Technology Process of CpFe(dppe)(CCC₆H₄-4-Me)

There total 2 articles about CpFe(dppe)(CCC₆H₄-4-Me) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 32843-51-9
[CpFeCl(dppe)]

: 766-97-2
4-n-methylphenylacetylene

: 1130297-85-6
CpFe(dppe)(CCC₆H₄-4-Me)

Guidance literature:: With DBU; In methanol; N2; Fe compd. and alkyne (slight excess) refluxed for 1 h, cooled, DBU (few drops) added, stirred for 10 min (ice bath); ppt. filtered off, washed (MeOH), dried (vac.), recrystd. (acetone/hexane), elem. anal.;
DOI:10.1016/j.ica.2011.10.067

Reference yield: 54.0%

: (Ph₃P)gold(I)CC(4-C₆H₄-CH₃)

: 32843-51-9
[CpFeCl(dppe)]

: 1130297-85-6
CpFe(dppe)(CCC₆H₄-4-Me)

Guidance literature:: With NH₄PF₆; DBU; In methanol; under N2 atm. suspn. Fe complex, Au complex and NH4PF6 in MeOH was heated at reflux for 1 h, DBU was added; react. mixt. was taken to dryness, residue was extd. with benzene, prep.TLC (hexane-acetone 7:3); elem. anal.;
DOI:10.1039/b809960j

Reference yield: 40.0%

: 1130297-85-6
CpFe(dppe)(CCC₆H₄-4-Me)

: 1-cyano-4-(dimethylamino)-pyridinium tetrafluoroborate

: [CpFe(dppe)(CC(CN)C₆H₄-4-Me)][BF₄]

Guidance literature:: In dichloromethane; acetonitrile; N2; MeCN soln. of B compd. added to DCM soln. of Ru compd. (1:1 molar ratio), mixt. stirred for 2 h; evapd., chromd. (TLC, acetone/hexane=6/4), crystd. (MeOH), elem. anal.;
DOI:10.1016/j.ica.2011.10.067