5-Methyl-3-oxo-hexanoic acid (1R,5R)-2-eth-(E)-ylidene-5-methyl-cyclohexyl ester

Base Information

Chemical Name:5-Methyl-3-oxo-hexanoic acid (1R,5R)-2-eth-(E)-ylidene-5-methyl-cyclohexyl ester
CAS No.:86238-51-9
Molecular Formula:C₁₆H₂₆O₃
Molecular Weight:266.381
Hs Code.:

Synonyms:5-Methyl-3-oxo-hexanoic acid (1R,5R)-2-eth-(E)-ylidene-5-methyl-cyclohexyl ester

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Chemical Property of 5-Methyl-3-oxo-hexanoic acid (1R,5R)-2-eth-(E)-ylidene-5-methyl-cyclohexyl ester

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Technology Process of 5-Methyl-3-oxo-hexanoic acid (1R,5R)-2-eth-(E)-ylidene-5-methyl-cyclohexyl ester

There total 4 articles about 5-Methyl-3-oxo-hexanoic acid (1R,5R)-2-eth-(E)-ylidene-5-methyl-cyclohexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 86238-56-4
(1R,5R)-2-Eth-(E)-ylidene-5-methyl-cyclohexanol

: 86238-51-9
5-Methyl-3-oxo-hexanoic acid (1R,5R)-2-eth-(E)-ylidene-5-methyl-cyclohexyl ester

Guidance literature:: In benzene; at 55 ℃;
DOI:10.1021/jo00160a047

Reference yield:

: 89-82-7,90449-51-7
pulegone

: 86238-51-9
5-Methyl-3-oxo-hexanoic acid (1R,5R)-2-eth-(E)-ylidene-5-methyl-cyclohexyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) p-TsOH, 2.) O₃, 3.) NaBH₄

2: 80 percent / pyridinium p-toluenesulfonate / acetone; H₂O / 36 h / Heating

3: 94 percent / NaBH₄, CeCl₃ / methanol / 0.08 h / Ambient temperature

4: 92 percent / benzene / 55 °C

With sodium tetrahydroborate; cerium(III) chloride; pyridinium p-toluenesulfonate; toluene-4-sulfonic acid; ozone; In methanol; water; acetone; benzene;
DOI:10.1021/jo00160a047

Reference yield:

: 86238-55-3
1-((R)-9-Methyl-1,4-dioxa-spiro[4.5]dec-6-yl)-ethanol

: 86238-51-9
5-Methyl-3-oxo-hexanoic acid (1R,5R)-2-eth-(E)-ylidene-5-methyl-cyclohexyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 80 percent / pyridinium p-toluenesulfonate / acetone; H₂O / 36 h / Heating

2: 94 percent / NaBH₄, CeCl₃ / methanol / 0.08 h / Ambient temperature

3: 92 percent / benzene / 55 °C

With sodium tetrahydroborate; cerium(III) chloride; pyridinium p-toluenesulfonate; In methanol; water; acetone; benzene;
DOI:10.1021/jo00160a047