[Cu(2,9-di-n-butyl-1,10-phenanthroline)(bis[2-(diphenylphosphino)phenyl]ether)]BF₄*acetonitrile

Base Information

• Chemical Name: [Cu(2,9-di-n-butyl-1,10-phenanthroline)(bis[2-(diphenylphosphino)phenyl]ether)]BF₄*acetonitrile
• CAS No.: 396723-85-6
• Molecular Formula: BF₄*C₂H₃N*C₅₆H₅₂CuN₂OP₂
• Molecular Weight: 1022.39
• Mol file: 396723-85-6.mol

Synonyms:[Cu(2,9-di-n-butyl-1,10-phenanthroline)(bis[2-(diphenylphosphino)phenyl]ether)]BF₄*acetonitrile

Chemical Property of [Cu(2,9-di-n-butyl-1,10-phenanthroline)(bis[2-(diphenylphosphino)phenyl]ether)]BF₄*acetonitrile

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Cu(2,9-di-n-butyl-1,10-phenanthroline)(bis[2-(diphenylphosphino)phenyl]ether)]BF₄*acetonitrile

There total 1 articles about [Cu(2,9-di-n-butyl-1,10-phenanthroline)(bis[2-(diphenylphosphino)phenyl]ether)]BF₄*acetonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

tetrakis(acetonitrile)copper(I)tetrafluoroborate + 2,9-di-n-butyl-1,10-phenanthroline (85575-93-5) + acetonitrile (75-05-8,26809-02-9) + bis[2-(diphenylphosphino)phenyl] ether (166330-10-5) → [Cu(2,9-di-n-butyl-1,10-phenanthroline)(bis[2-(diphenylphosphino)phenyl]ether)]BF4*acetonitrile (396723-85-6)

Guidance literature:

In dichloromethane; mixt. (Cu(NCMe)4)BF4 and DPEphos in CH2Cl2 was stirred at 25°C for 2 h, treated with soln. dbp in CH2Cl2, and stirred for 1 h, soln. was concd., MeCN was added, Et2O diffusion; crystals were washed with Et2O; elem. anal.;

DOI:10.1021/ic0201809

upstream raw materials:

2,9-di-n-butyl-1,10-phenanthroline

acetonitrile

bis[2-(diphenylphosphino)phenyl] ether