Technology Process of C28H40OS2Si
There total 4 articles about C28H40OS2Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C23H32OS2Si;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at 0 - 20 ℃;
for 1h;
prenyl bromide;
In
tetrahydrofuran; hexane;
at -40 - 20 ℃;
for 6h;
DOI:10.1021/ol500849m
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: sodium hydride / tetrahydrofuran / 1 h / 0 - 20 °C
1.2: 0 - 20 °C
2.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 0.75 h / -78 °C
2.2: 0.5 h / -78 - 0 °C
3.1: magnesium bromide ethyl etherate / diethyl ether / 1 h / 0 °C
4.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / 0 - 20 °C
4.2: 6 h / -40 - 20 °C
With
n-butyllithium; oxalyl dichloride; sodium hydride; magnesium bromide ethyl etherate; dimethyl sulfoxide;
In
tetrahydrofuran; diethyl ether; hexane; dichloromethane;
2.1: |Swern Oxidation / 2.2: |Swern Oxidation;
DOI:10.1021/ol500849m
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 0.75 h / -78 °C
1.2: 0.5 h / -78 - 0 °C
2.1: magnesium bromide ethyl etherate / diethyl ether / 1 h / 0 °C
3.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / 0 - 20 °C
3.2: 6 h / -40 - 20 °C
With
n-butyllithium; oxalyl dichloride; magnesium bromide ethyl etherate; dimethyl sulfoxide;
In
tetrahydrofuran; diethyl ether; hexane; dichloromethane;
1.1: |Swern Oxidation / 1.2: |Swern Oxidation;
DOI:10.1021/ol500849m
