Tris<4-(1,3-dioxacyclopent-2-yl)phenyl>phosphane

Base Information

• Chemical Name: Tris<4-(1,3-dioxacyclopent-2-yl)phenyl>phosphane
• CAS No.: 173726-42-6
• Molecular Formula: C₂₇H₂₇O₆P
• Molecular Weight: 478.482
• Mol file: 173726-42-6.mol

Synonyms:Tris<4-(1,3-dioxacyclopent-2-yl)phenyl>phosphane

Chemical Property of Tris<4-(1,3-dioxacyclopent-2-yl)phenyl>phosphane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Tris<4-(1,3-dioxacyclopent-2-yl)phenyl>phosphane

There total 2 articles about Tris<4-(1,3-dioxacyclopent-2-yl)phenyl>phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

p-bromobenzaldehyde 1,3-dioxolane (10602-01-4) → Tris<4-(1,3-dioxacyclopent-2-yl)phenyl>phosphane (173726-42-6)

Guidance literature:

With magnesium; phosphorus trichloride; Yield given. Multistep reaction; 1.) THF, 2.) r.t., 12 h; reflux, 3 h;

DOI:10.1021/jp952854p

Reference yield:

4-bromo-benzaldehyde (1122-91-4) → Tris<4-(1,3-dioxacyclopent-2-yl)phenyl>phosphane (173726-42-6)

Guidance literature:

Multi-step reaction with 2 steps

1.1: toluene-4-sulfonic acid / toluene / 12 h / Reflux

2.1: magnesium / tetrahydrofuran / Sonication

2.2: 15 h / 0 °C / Reflux

With toluene-4-sulfonic acid; magnesium; In tetrahydrofuran; toluene;

DOI:10.1002/chem.202002150

Reference yield: 67.0%

Tris<4-(1,3-dioxacyclopent-2-yl)phenyl>phosphane (173726-42-6) → 4-[bis(4-formylphenyl)phosphanyl]benzaldehyde (67753-41-7)

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; water; for 0.25h; Reflux;

DOI:10.1002/chem.202002150

upstream raw materials:

p-bromobenzaldehyde 1,3-dioxolane

4-bromo-benzaldehyde

Downstream raw materials:

4-[bis(4-formylphenyl)phosphanyl]benzaldehyde

Refernces

• 1、 Chalier, Florence,Berchadsky, Yves,Finet, Jean-Pierre,Gronchi, Gerard,Marque, Sylvain,Tordo, Paul. "Synthesis, X-ray geometry, and anodic behavior of tris[2-(hydroxymethyl)phenyl]phosphane". . p. 4323 - 4330. Retrieved 2007/10/03.