4-((6,6,7,7,8,8,9,9,10,10,11,11,11-tridecafluoro-2-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)undecyl)oxy)phenyl-α-L-rhamnopyranoside

Base Information

Chemical Name:4-((6,6,7,7,8,8,9,9,10,10,11,11,11-tridecafluoro-2-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)undecyl)oxy)phenyl-α-L-rhamnopyranoside
CAS No.:1354049-48-1
Molecular Formula:C₃₂H₃₀F₂₆O₆
Molecular Weight:1004.55
Hs Code.:

Synonyms:4-((6,6,7,7,8,8,9,9,10,10,11,11,11-tridecafluoro-2-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)undecyl)oxy)phenyl-α-L-rhamnopyranoside

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Chemical Property of 4-((6,6,7,7,8,8,9,9,10,10,11,11,11-tridecafluoro-2-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)undecyl)oxy)phenyl-α-L-rhamnopyranoside

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Technology Process of 4-((6,6,7,7,8,8,9,9,10,10,11,11,11-tridecafluoro-2-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)undecyl)oxy)phenyl-α-L-rhamnopyranoside

There total 9 articles about 4-((6,6,7,7,8,8,9,9,10,10,11,11,11-tridecafluoro-2-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)undecyl)oxy)phenyl-α-L-rhamnopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 4-((6,6,7,7,8,8,9,9,10,10,11,11,11-tridecafluoro-2-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)undecyl)oxy)phenyl-2,3,4-tri-O-acetyl-α-L-rhamnopyranoside

: 1354049-48-1
4-((6,6,7,7,8,8,9,9,10,10,11,11,11-tridecafluoro-2-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)undecyl)oxy)phenyl-α-L-rhamnopyranoside

Guidance literature:: With potassium carbonate; In methanol; at 20 ℃; for 2h;
DOI:10.1039/c1cc16022b

Reference yield:

: 917379-63-6
6,6,7,7,8,8,9,9,10,10,11,11,11-tridecafluoro-2-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-nonyl)-undecanoic acid

: 1354049-48-1
4-((6,6,7,7,8,8,9,9,10,10,11,11,11-tridecafluoro-2-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)undecyl)oxy)phenyl-α-L-rhamnopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: lithium aluminium tetrahydride / diethyl ether / 12 h / 0 - 22 °C

2: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 6 h / 20 °C / Reflux

3: trimethylsilyl trifluoromethanesulfonate / toluene / 0.33 h / 0 °C

4: potassium carbonate / methanol / 2 h / 20 °C

With lithium aluminium tetrahydride; trimethylsilyl trifluoromethanesulfonate; di-isopropyl azodicarboxylate; potassium carbonate; triphenylphosphine; In tetrahydrofuran; methanol; diethyl ether; toluene; 2: Mitsunobu reaction;
DOI:10.1039/c1cc16022b

Reference yield:

: 917379-64-7
6,6,7,7,8,8,9,9,10,10,11,11,11-tridecafluoro-2-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)undecan-1-ol

: 1354049-48-1
4-((6,6,7,7,8,8,9,9,10,10,11,11,11-tridecafluoro-2-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)undecyl)oxy)phenyl-α-L-rhamnopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 6 h / 20 °C / Reflux

2: trimethylsilyl trifluoromethanesulfonate / toluene / 0.33 h / 0 °C

3: potassium carbonate / methanol / 2 h / 20 °C

With trimethylsilyl trifluoromethanesulfonate; di-isopropyl azodicarboxylate; potassium carbonate; triphenylphosphine; In tetrahydrofuran; methanol; toluene; 1: Mitsunobu reaction;
DOI:10.1039/c1cc16022b