5'-(4-(bis(4-(hexyloxy)phenyl)amino)naphthalen-1-yl)-2,2'-bithiophene-5-carbaldehy

Base Information

Chemical Name:5'-(4-(bis(4-(hexyloxy)phenyl)amino)naphthalen-1-yl)-2,2'-bithiophene-5-carbaldehy
CAS No.:1374559-68-8
Molecular Formula:C₄₃H₄₅NO₃S₂
Molecular Weight:687.967
Hs Code.:

Synonyms:5'-(4-(bis(4-(hexyloxy)phenyl)amino)naphthalen-1-yl)-2,2'-bithiophene-5-carbaldehy

Suppliers and Price of 5'-(4-(bis(4-(hexyloxy)phenyl)amino)naphthalen-1-yl)-2,2'-bithiophene-5-carbaldehy

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 5'-(4-(bis(4-(hexyloxy)phenyl)amino)naphthalen-1-yl)-2,2'-bithiophene-5-carbaldehy

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 5'-(4-(bis(4-(hexyloxy)phenyl)amino)naphthalen-1-yl)-2,2'-bithiophene-5-carbaldehy

There total 3 articles about 5'-(4-(bis(4-(hexyloxy)phenyl)amino)naphthalen-1-yl)-2,2'-bithiophene-5-carbaldehy which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

: 1374559-66-6
4-(2,2'-bithiophen-5-yl)-N,N-bis(4-(hexyloxy)phenyl)naphthalen-1-amine

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 1374559-68-8
5'-(4-(bis(4-(hexyloxy)phenyl)amino)naphthalen-1-yl)-2,2'-bithiophene-5-carbaldehy

Guidance literature:: 4-(2,2'-bithiophen-5-yl)-N,N-bis(4-(hexyloxy)phenyl)naphthalen-1-amine; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

N,N-dimethyl-formamide; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 10h;

With hydrogenchloride; In tetrahydrofuran; hexane; water; for 0.5h;
DOI:10.1002/asia.201100972

Reference yield:

: 1374559-62-2
C₃₄H₄₁NO₂

: 1374559-68-8
5'-(4-(bis(4-(hexyloxy)phenyl)amino)naphthalen-1-yl)-2,2'-bithiophene-5-carbaldehy

Guidance literature:: Multi-step reaction with 3 steps

1.1: N-Bromosuccinimide / N,N-dimethyl-formamide / 10 h / 20 °C / Cooling with ice

2.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

2.2: 10 h / -78 - 20 °C

2.3: 10 h / 80 °C / Inert atmosphere

3.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

3.2: 10 h / -78 - 20 °C

3.3: 0.5 h

With N-Bromosuccinimide; n-butyllithium; In tetrahydrofuran; hexane; N,N-dimethyl-formamide; 2.3: Stille coupling;
DOI:10.1002/asia.201100972

Reference yield:

: 1374559-64-4
4-bromo-N,N-bis(4-(hexyloxy)phenyl)naphthalen-1-amine

: 1374559-68-8
5'-(4-(bis(4-(hexyloxy)phenyl)amino)naphthalen-1-yl)-2,2'-bithiophene-5-carbaldehy

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

1.2: 10 h / -78 - 20 °C

1.3: 10 h / 80 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

2.2: 10 h / -78 - 20 °C

2.3: 0.5 h

With n-butyllithium; In tetrahydrofuran; hexane; 1.3: Stille coupling;
DOI:10.1002/asia.201100972