Technology Process of C68H124O10S2Si3
There total 26 articles about C68H124O10S2Si3 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: TBAI; DIEA / CH2Cl2
2.1: K2CO3 / methanol
3.1: t-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / 0.07 h / -78 °C
3.2: 75 percent / tetrahydrofuran / 0.17 h
4.1: SO3*pyr; DMSO
With
pyridine-SO3 complex; tert.-butyl lithium; tetra-(n-butyl)ammonium iodide; potassium carbonate; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine;
In
tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane;
4.1: Parikh-Doering oxidation;
DOI:10.1021/ja0289649
- Guidance literature:
-
Multi-step reaction with 17 steps
1.1: 2,6-lutidine
2.1: LiBH4 / methanol; diethyl ether
3.1: DMAP; Et3N
4.1: OsO4; NMO
5.1: aq. NaIO4
6.1: 97 percent / toluene / 17 h / -78 °C
7.1: K2CO3 / methanol
8.1: PPTs / acetone
9.1: 9-BBN / tetrahydrofuran; diethyl ether
9.2: aq. H2O2; NaOH / tetrahydrofuran; diethyl ether
10.1: Et3N
11.1: DDQ / H2O
12.1: Dess-Martin periodinane
13.1: K2CO3 / methanol
14.1: 92 percent / (PhO)3PCH3I; DIEA / tetrahydrofuran / 0.42 h
15.1: t-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / 0.07 h / -78 °C
15.2: 75 percent / tetrahydrofuran / 0.17 h
16.1: SO3*pyr; DMSO
With
2,6-dimethylpyridine; dmap; sodium periodate; osmium(VIII) oxide; lithium borohydride; 9-borabicyclo[3.3.1]nonane dimer; N-methyl-2-indolinone; pyridine-SO3 complex; methyltriphenoxyphosphonium iodide; tert.-butyl lithium; pyridinium p-toluenesulfonate; potassium carbonate; Dess-Martin periodane; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone;
In
tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; water; acetone; toluene;
6.1: Roush crotylation / 12.1: Dess-Martin oxidation / 13.1: Wittig olefination / 17.1: Parikh-Doering oxidation;
DOI:10.1021/ja0289649
- Guidance literature:
-
Multi-step reaction with 19 steps
1.1: DMSO; (COCl)2; NEt3 / -78 - 20 °C
2.1: Bu2BOTf; Et3N
3.1: 2,6-lutidine
4.1: LiBH4 / methanol; diethyl ether
5.1: DMAP; Et3N
6.1: OsO4; NMO
7.1: aq. NaIO4
8.1: 97 percent / toluene / 17 h / -78 °C
9.1: K2CO3 / methanol
10.1: PPTs / acetone
11.1: 9-BBN / tetrahydrofuran; diethyl ether
11.2: aq. H2O2; NaOH / tetrahydrofuran; diethyl ether
12.1: Et3N
13.1: DDQ / H2O
14.1: Dess-Martin periodinane
15.1: K2CO3 / methanol
16.1: 92 percent / (PhO)3PCH3I; DIEA / tetrahydrofuran / 0.42 h
17.1: t-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / 0.07 h / -78 °C
17.2: 75 percent / tetrahydrofuran / 0.17 h
18.1: SO3*pyr; DMSO
With
2,6-dimethylpyridine; dmap; sodium periodate; osmium(VIII) oxide; lithium borohydride; 9-borabicyclo[3.3.1]nonane dimer; N-methyl-2-indolinone; oxalyl dichloride; pyridine-SO3 complex; di-n-butylboryl trifluoromethanesulfonate; methyltriphenoxyphosphonium iodide; tert.-butyl lithium; pyridinium p-toluenesulfonate; potassium carbonate; Dess-Martin periodane; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone;
In
tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; water; acetone; toluene;
1.1: Swern oxidation / 8.1: Roush crotylation / 14.1: Dess-Martin oxidation / 15.1: Wittig olefination / 19.1: Parikh-Doering oxidation;
DOI:10.1021/ja0289649
